Synthesis of dendronized, chiral conjugated polymers with appendant Frechet-type dendrons
文献类型：期刊论文
| 作者 | Jiang, J; Liu, HW; Zhao, YL; Chen, CF; Xi, F |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2002-04-15 |
| 卷号 | 40期号:8页码:1167-1172 |
| 关键词 | Chiral Binaphthyl-based Polyarylene Frechet-type Dendron Suzuki Polycondensation (Spc) Conjugated Polymers |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.10205 |
| 英文摘要 | New chiral binaphthyl-based polyarylenes [(S)-3a and (S)-3b] with appendant Frechet-type poly(aryl ether,) dendrons (first generation and second generation) were synthesized with Suzuki polycondensation from chiral (S)-6,6'-dibromo-2,2'-didendron-substituted 1,1'-binaphthyl derivatives and p-phenylene diboronic acid. The polymers were studied with circular dichroism, fluorescence, and ultraviolet-visible spectra. Laser light scattering measurements of (S)-3a and (S)-3b showed that their weight-average molecular weights were 2.39 X 10(5) and 1.09 X 10(4), respectively. The specific optical rotation [alpha](D) was -59.6 for (S)-3a and -62.7 for (S)-3b. These dendronized conjugated polymers exhibited good thermal stability. The glass-transition temperatures and the initial decomposition temperatures were 187.5 and 265.3 degreesC for (S)-3a and 173.8 and 308.9 degreesC for (S)-3b, respectively. (S)-3a and (S)-3b had high fluorescence quantum efficiencies, 87 and 91%, respectively, in tetrahydrofuran. (C) 2002 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000174551800027 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79559]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, F |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, J,Liu, HW,Zhao, YL,et al. Synthesis of dendronized, chiral conjugated polymers with appendant Frechet-type dendrons[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2002,40(8):1167-1172. |
| APA | Jiang, J,Liu, HW,Zhao, YL,Chen, CF,&Xi, F.(2002).Synthesis of dendronized, chiral conjugated polymers with appendant Frechet-type dendrons.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,40(8),1167-1172. |
| MLA | Jiang, J,et al."Synthesis of dendronized, chiral conjugated polymers with appendant Frechet-type dendrons".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 40.8(2002):1167-1172. |
入库方式： OAI收割
来源：化学研究所
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