Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb)
文献类型：期刊论文
| 作者 | Cheng, JH; Cui, DM; Chen, WQ; Tang, T; Huang, BT |
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2002-09-16 |
| 卷号 | 658期号:1-2页码:153-158 |
| 关键词 | Tetrahydrofurfurylindenyl Synthesis Lanthanide Chlorides Crystal Structures |
| ISSN号 | 0022-328X |
| 英文摘要 | Reaction of anhydrous lanthanide trichlorides with tetrahydrofurfuryl indenyl lithium in THF afforded bis(tetrahydrofurfurylindenyl) lanthanocene chlorides complexes (C4H7OCH2C9H6)(2) LnCl, Ln = Nd (1), Sm (2), Dy (3), Ho (4), Er (5), Yb (6). The X-ray crystallographic structures of all the six complexes were determined and these indicate that they are unsolvated nine-coordinate monomeric complexes with a trans arrangement of both the sidearm and indenyl rings in the solid state. They belong to the same crystal system (orthorhombic) and space group (P2(1)2(1)2(1)) with the same structure. Especially, they are more stable to air and moisture than the corresponding unsubstituted indenyl lanthanide complexes. (C) 2002 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000178258500019 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79577]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, T |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Jilin Inst Technol, Dept Chem Engn, Changchun 130012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, JH,Cui, DM,Chen, WQ,et al. Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb)[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2002,658(1-2):153-158. |
| APA | Cheng, JH,Cui, DM,Chen, WQ,Tang, T,&Huang, BT.(2002).Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb).JOURNAL OF ORGANOMETALLIC CHEMISTRY,658(1-2),153-158. |
| MLA | Cheng, JH,et al."Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb)".JOURNAL OF ORGANOMETALLIC CHEMISTRY 658.1-2(2002):153-158. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。