中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Relationships between structures and hydrolytic stability of silazane compounds

文献类型:期刊论文

作者Jiang, J; Peng, WQ; Zheng, ZM; Xu, CH; Xie, ZM
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
出版日期2002-06-01
卷号23期号:6页码:1189-1192
关键词Silazane Compound Hydrolytic Stability Steric Hindrance Ring Strength
ISSN号0251-0790
英文摘要Relationships between structures of a series of silazane compounds and their hydrolytic stability were investigated by contacting silazane compounds directly with water vapor. It was indicated that steric hindrance of substituents strongly influenced hydrolytic stability of silazane compounds. Compounds with bigger substituents had better hydrolytic stability. As for cyclosilazanes, hydrolytic stability was also dependent on ring strength. However, steric hindrance played more dominant roles. Cyclosilazanes with phenyl substituents, hexaphenylcyclotrisilazane and polymeric compounds containing Si-N bond were of excellent hydrolytic stability due to high steric hindrance.
语种英语
WOS记录号WOS:000176272300054
出版者HIGHER EDUCATION PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/79609]  
专题中国科学院化学研究所
通讯作者Xie, ZM
作者单位Chinese Acad Sci, Ctr Mat Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Jiang, J,Peng, WQ,Zheng, ZM,et al. Relationships between structures and hydrolytic stability of silazane compounds[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(6):1189-1192.
APA Jiang, J,Peng, WQ,Zheng, ZM,Xu, CH,&Xie, ZM.(2002).Relationships between structures and hydrolytic stability of silazane compounds.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(6),1189-1192.
MLA Jiang, J,et al."Relationships between structures and hydrolytic stability of silazane compounds".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.6(2002):1189-1192.

入库方式: OAI收割

来源:化学研究所

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