Highly active vinyl-polymerization of norbornene by [2-methyl-8-(diphenylphosphino)quinoline]nickel(II) dichloride/methylaluminoxane
文献类型：期刊论文
| 作者 | Yang, HJ; Li, ZL; Sun, WH |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2003-10-01 |
| 卷号 | 206期号:1-2页码:23-28 |
| 关键词 | Vinyl Polynorbornene High Activity High Molecular Weight Wide Molecular Weight Distribution Amorphous Polymers |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/S1381-1169(03)00426-6 |
| 英文摘要 | Polymerization of norbornene has been promoted by a catalyst system composed of [2-methyl-8-(diphenylphosphino)quinoline]nickel dichloride and MAO. The catalytic system showed high activity (activity < 1.70 x 10(8) g-PNB/mol-Ni h) for vinyl addition type polymerization. The resultant polynorbornenes possessed high molecular weight (M-w < 2.08 x 10(6) g/mol) with wide molecular weight distribution (M-w/M-n < 19.20), and were soluble, showing no crystallinity in the solid state. The catalytic activity, molecular weight as well as polydispersity of the resultant polymer can be controlled over a wide range by varying the reaction parameters. (C) 2003 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000185399000002 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79801]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, WH |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, HJ,Li, ZL,Sun, WH. Highly active vinyl-polymerization of norbornene by [2-methyl-8-(diphenylphosphino)quinoline]nickel(II) dichloride/methylaluminoxane[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2003,206(1-2):23-28. |
| APA | Yang, HJ,Li, ZL,&Sun, WH.(2003).Highly active vinyl-polymerization of norbornene by [2-methyl-8-(diphenylphosphino)quinoline]nickel(II) dichloride/methylaluminoxane.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,206(1-2),23-28. |
| MLA | Yang, HJ,et al."Highly active vinyl-polymerization of norbornene by [2-methyl-8-(diphenylphosphino)quinoline]nickel(II) dichloride/methylaluminoxane".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 206.1-2(2003):23-28. |
入库方式： OAI收割
来源：化学研究所
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