Hydrogen-bonding-directed template synthesis of novel stereo-regular organo-bridged ladder-like polymethylsiloxane
文献类型：期刊论文
| 作者 | Tang, HD; Sun, J; Zhou, XS; Fu, PF; Xie, P; Zhang, RB |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2003-01-30 |
| 卷号 | 204期号:1页码:155-163 |
| 关键词 | Ladder-like Polymethylsiloxane Self-assembly Stepwise Coupling Polymerization Templates |
| ISSN号 | 1022-1352 |
| 英文摘要 | A novel stereo-regular organo-bridged ladder-like polymethylsiloxane (LPMS) was synthesized by a stepwise coupling polymerization on the basis of an amido H-bonding-assisted self-assembling template. The monomer N,N'-bis{4-[3-(diethoxymethysilyl)proposyl]-phenyl}terephthalamide (M), prepared by hydrosilylation reaction at high temperature, was hydrolyzed in a dilute solution at a low temperature to form a ladder-like supramolecular intermediate through amido H bonding interactions, which was further condensed to form the polymer LPMS. A combination of techniques including H-1 NMR, Si-29 NMR, and FT-IR spetroscopies X-ray diffraction (XRD), and differential scanning calorimetry (DSC) were used to characterize the titled polymer LPMS, and the results indicate that the polymer possesses an ordered ladder-like structure. |
| 语种 | 英语 |
| WOS记录号 | WOS:000181508300019 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79835]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China 2.Dow Corning Corp, New Ventures R&D, Midland, MI 48686 USA |
| 推荐引用方式 GB/T 7714 | Tang, HD,Sun, J,Zhou, XS,et al. Hydrogen-bonding-directed template synthesis of novel stereo-regular organo-bridged ladder-like polymethylsiloxane[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2003,204(1):155-163. |
| APA | Tang, HD,Sun, J,Zhou, XS,Fu, PF,Xie, P,&Zhang, RB.(2003).Hydrogen-bonding-directed template synthesis of novel stereo-regular organo-bridged ladder-like polymethylsiloxane.MACROMOLECULAR CHEMISTRY AND PHYSICS,204(1),155-163. |
| MLA | Tang, HD,et al."Hydrogen-bonding-directed template synthesis of novel stereo-regular organo-bridged ladder-like polymethylsiloxane".MACROMOLECULAR CHEMISTRY AND PHYSICS 204.1(2003):155-163. |
入库方式： OAI收割
来源：化学研究所
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