中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
H-bonding assisted template synthesis of a novel ladder-like organo-bridged polymethylsiloxane

文献类型:期刊论文

作者Sun, J; Tang, HD; Jiang, JQ; Xie, P; Zhang, RB; Fu, PF; Wu, Q
刊名POLYMER
出版日期2003-05-01
卷号44期号:10页码:2867-2874
关键词H-bonding Assembly Template Synthesis Ladder-like Polymers
ISSN号0032-3861
DOI10.1016/S0032-3861(03)00210-6
英文摘要A novel soluble aryl amide-bridged ladder-like polymethylsiloxane (ALPS) was synthesized via a stepwise coupling polymerization by means of H-bonding self-assembling template. The new monomer N,N'-di(4-methyldiethoxysiloxyl-phenyl)-terephthaloyI amide, prepared by dehydrocoupling reaction of N,N'-di(4-hydroxy-phenyl)-terephthaloyl amide with methyldiethoxysilane, was hydrolyzed in a dilute solution at low temperature to form a proposed ladder-like supramolecular intermediate through amido H-bonding interaction, which was further condensed to form polymer ALPS using dibuthyltindilaurate as catalyst. A combination of techniques including H-1 NMR, Si-29 NMR, FTIR, X-ray diffraction (XRD), DSC, and light scattering were used to characterize the titled polymer ALPS. The results indicate the polymer ALPS possesses an ordered ladder-like architecture. (C) 2003 Elsevier Science Ltd. All rights reserved.
语种英语
WOS记录号WOS:000182557100007
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/79883]  
专题中国科学院化学研究所
通讯作者Tang, HD
作者单位1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
2.Dow Corning Corp, New Ventures R&D, Midland, MI 48686 USA
3.Nankai Univ, State Key Lab Funct Polymer Mat Adsorpt & Separat, Tianjin 300071, Peoples R China
推荐引用方式
GB/T 7714
Sun, J,Tang, HD,Jiang, JQ,et al. H-bonding assisted template synthesis of a novel ladder-like organo-bridged polymethylsiloxane[J]. POLYMER,2003,44(10):2867-2874.
APA Sun, J.,Tang, HD.,Jiang, JQ.,Xie, P.,Zhang, RB.,...&Wu, Q.(2003).H-bonding assisted template synthesis of a novel ladder-like organo-bridged polymethylsiloxane.POLYMER,44(10),2867-2874.
MLA Sun, J,et al."H-bonding assisted template synthesis of a novel ladder-like organo-bridged polymethylsiloxane".POLYMER 44.10(2003):2867-2874.

入库方式: OAI收割

来源:化学研究所

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