Photoinduced electron transfer reaction of mono-(6-deoxy-p-nitrobenzylamino)-beta-cyclodextrin with naphthalene derivatives
文献类型：期刊论文
| 作者 | Wang, YH; Fu, Y; Zhang, HM; Ye, JP; Guo, QX |
| 刊名 | RESEARCH ON CHEMICAL INTERMEDIATES
 |
| 出版日期 | 2003 |
| 卷号 | 29期号:2页码:169-180 |
| 关键词 | Cyclodextrin Host-guest Interaction Naphthalene Derivatives Photoinduced Electron Transfer |
| ISSN号 | 0922-6168 |
| 英文摘要 | The fluorescence of a number of naphthalene derivatives was quenched by 6-deoxy-p-nitrobenzylamino-beta-cyclodextrin (NACD) in aqueous solution. The origin of the quenching was attributed to the electron transfer from the excited naphthalene groups to the ground state p-nitrobenzyl group of NACD. Both steady-state and time-resolved fluorescence measurements revealed that there were two routes of electron transfer, i.e. (1) electron transfer between the free donor and free acceptor in solution and (2) electron transfer between the donor and acceptor bound in a supramolcular assemble. The evidence collected demonstrates that the latter route was very efficient. As a result, the electron transfer rate and quantum yield of the fluorescence quenching in the present host-guest system were appreciably large. |
| 语种 | 英语 |
| WOS记录号 | WOS:000183329000005 |
| 出版者 | VSP BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80073]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Guo, QX |
| 作者单位 | 1.Univ Sci & Technol China, Dept Chem, Anhua 230026, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China 3.Lanzhou Univ, Natl Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YH,Fu, Y,Zhang, HM,et al. Photoinduced electron transfer reaction of mono-(6-deoxy-p-nitrobenzylamino)-beta-cyclodextrin with naphthalene derivatives[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2003,29(2):169-180. |
| APA | Wang, YH,Fu, Y,Zhang, HM,Ye, JP,&Guo, QX.(2003).Photoinduced electron transfer reaction of mono-(6-deoxy-p-nitrobenzylamino)-beta-cyclodextrin with naphthalene derivatives.RESEARCH ON CHEMICAL INTERMEDIATES,29(2),169-180. |
| MLA | Wang, YH,et al."Photoinduced electron transfer reaction of mono-(6-deoxy-p-nitrobenzylamino)-beta-cyclodextrin with naphthalene derivatives".RESEARCH ON CHEMICAL INTERMEDIATES 29.2(2003):169-180. |
入库方式： OAI收割
来源：化学研究所
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