First determination of ionization energies of phenylnitrene
文献类型：期刊论文
| 作者 | Che, HJ; Bi, HM; Ding, R; Wang, D; Meng, LP; Zheng, SJ; Wang, DX; Mok, DKW; Chau, FT |
| 刊名 | CHEMICAL PHYSICS LETTERS
 |
| 出版日期 | 2003-12-05 |
| 卷号 | 382期号:3-4页码:291-296 |
| ISSN号 | 0009-2614 |
| DOI | 10.1016/j.cplett.2003.10.064 |
| 英文摘要 | The continuous flowing beams of the triplet state phenylnitrene (PhN) species have been generated by respective pyrolysis of PhN3 at 83(+/-0.5) degreesC and phenylisocyanate (PhNCO) at 105(+/-0.5) degreesC in the quartz inlet tube loosely filled with a 30 A molecular sieve powder supported on the quartz wool. PE spectrum of PhN is recorded in situ for the first time. The ionization energies, corresponding to different ionic states of PhN+, are determined by PES experiment and both G2 and DFT calculations. The study indicates that PhN is a diradical with C-2v symmetry and has a (3)A(2) ground state. (C) 2003 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000186927700011 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80119]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, DX |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China 3.Hebei Normal Univ, Open Lab Computat Quantum Chem, Shijiazhuang 050091, Peoples R China |
| 推荐引用方式 GB/T 7714 | Che, HJ,Bi, HM,Ding, R,et al. First determination of ionization energies of phenylnitrene[J]. CHEMICAL PHYSICS LETTERS,2003,382(3-4):291-296. |
| APA | Che, HJ.,Bi, HM.,Ding, R.,Wang, D.,Meng, LP.,...&Chau, FT.(2003).First determination of ionization energies of phenylnitrene.CHEMICAL PHYSICS LETTERS,382(3-4),291-296. |
| MLA | Che, HJ,et al."First determination of ionization energies of phenylnitrene".CHEMICAL PHYSICS LETTERS 382.3-4(2003):291-296. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。