Synthesis and properties of novel liquid ester-free reworkable cycloaliphatic diepoxides for electronic packaging application
文献类型：期刊论文
| 作者 | Wang, ZG; Xie, MR; Zhao, YF; Yu, YZ; Fang, SB |
| 刊名 | POLYMER
 |
| 出版日期 | 2003-02-01 |
| 卷号 | 44期号:4页码:923-929 |
| 关键词 | Cycloaliphatic Diepoxide Reworkability Electronic Packaging |
| ISSN号 | 0032-3861 |
| 英文摘要 | Four novel liquid cycloaliphatic diepoxides, with two epoxycyclohexyl moieties linked via-O-(EpoI), -OCH2CH2O-(EpoII), -OCH (CH3)CH2O- (EpoIII), -OCH(CH3)CH2CH(CH3)O-(EpoIV), respectively, and their diene precursors were synthesized and characterized. These diepoxides could be readily cured with hexahydro-4-methylphthalic anhydride (HMPA) using Iron (III) acetylacetonate as curing accelerator. The thermal and mechanical properties of cured products were examined by differential scanning calorimetry (DSC), thermal mechanical analysis (TMA) and dynamic mechanical analysis (DMA). The thermogravimetric analysis (TGA) data revealed that, the cured EpoI and EpoII had similar thermal decomposition onset temperature to the commercial ERL-4221(TM) (> 300degreesC), whereas the cured EopIII and EpoIV, having secondary or tertiary carbon-ether linkages, started to decompose at obviously lower temperature (around 220degreesC), which just lay in the desired reworkability temperature range (200-300degreesC). The higher glass transition temperature (> 120degreesC) and moderately low thermal decomposition temperature made EpoIII and EpoIV suitable candidates for future reworkable flip chip electronic packaging application. (C) 2002 Elsevier Science Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000180585400002 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80177]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, ZG |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, ZG,Xie, MR,Zhao, YF,et al. Synthesis and properties of novel liquid ester-free reworkable cycloaliphatic diepoxides for electronic packaging application[J]. POLYMER,2003,44(4):923-929. |
| APA | Wang, ZG,Xie, MR,Zhao, YF,Yu, YZ,&Fang, SB.(2003).Synthesis and properties of novel liquid ester-free reworkable cycloaliphatic diepoxides for electronic packaging application.POLYMER,44(4),923-929. |
| MLA | Wang, ZG,et al."Synthesis and properties of novel liquid ester-free reworkable cycloaliphatic diepoxides for electronic packaging application".POLYMER 44.4(2003):923-929. |
入库方式： OAI收割
来源：化学研究所
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