Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization
文献类型：期刊论文
| 作者 | Xu, YA; Xue, H; Zhang, SB; Gao, LX; Ding, MX |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2003-04-01 |
| 卷号 | 24期号:4页码:748-750 |
| 关键词 | Optically Active Polymer Menthyl Methacrylate Anionic Polymerization Group Transfer Polymerization Radical Polymerization |
| ISSN号 | 0251-0790 |
| 英文摘要 | The optically active polymers of ( -) -menthyl methacrylate were obtained by anionic, group transfer polymerization (GTP) and radical polymerization methods. The influences of different polymerization methods on specific rotation, yield and stereoregularity of polymers were studied. In the fluorene lithium and, (S, S)-(+)-2, 3-dimethoxy-1, 4-bis (dimethylamino) butane [(+)-DDB] complex initiative system, the specific rotation values rise slightly with the increase of molecular weight. There is no obvious difference in the specific rotation values of PMnMAs obtained by different, polymerization methods, but there is an obvious variation in stereoregularity of the polymers. And the change of the optical activity of PMn-MA is slight as compared with the variation of the stereoregularity. The tacticity of polymers is mainly syndiotactic. |
| 语种 | 英语 |
| WOS记录号 | WOS:000182512000047 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80223]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ding, MX |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, YA,Xue, H,Zhang, SB,et al. Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,24(4):748-750. |
| APA | Xu, YA,Xue, H,Zhang, SB,Gao, LX,&Ding, MX.(2003).Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,24(4),748-750. |
| MLA | Xu, YA,et al."Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 24.4(2003):748-750. |
入库方式： OAI收割
来源：化学研究所
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