Adlayer structures of calixarenes on Au(111) surface studied with STM
文献类型：期刊论文
| 作者 | Pan, GB; Bu, JH; Wang, D; Liu, JM; Wan, LJ; Zheng, QY; Bai, CL |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2003-11-27 |
| 卷号 | 107期号:47页码:13111-13116 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp030671u |
| 英文摘要 | In-situ scanning tunneling microscopy (STM) and cyclic voltammetry have been employed to investigate conformation-related adlayer structures of four calixarenes, three calix[4]arenes with specific conformations and one calix[6]arene. All the molecules form ordered adlayers on the Au(111) surface in 0.1 M HClO4 under the potential control. For calix[4]arenes, different adlayers are organized on the basis of their specific conformations, indicating that conformations might be used to obtain desired structures. A well-defined adlayer is observed for calix[6]arene. The results demonstrate that the conformation of calixarenes can be immobilized on the Au(I 11) surface through adsorption, although various conformations of the molecule are reported in solution. The reason is ascribed to the intermolecular and molecule-substrate interactions. On the basis of high-resolution STM images, structural models are tentatively proposed for the ordered adlayers of calixarenes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000186762200029 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80265]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, LJ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, GB,Bu, JH,Wang, D,et al. Adlayer structures of calixarenes on Au(111) surface studied with STM[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2003,107(47):13111-13116. |
| APA | Pan, GB.,Bu, JH.,Wang, D.,Liu, JM.,Wan, LJ.,...&Bai, CL.(2003).Adlayer structures of calixarenes on Au(111) surface studied with STM.JOURNAL OF PHYSICAL CHEMISTRY B,107(47),13111-13116. |
| MLA | Pan, GB,et al."Adlayer structures of calixarenes on Au(111) surface studied with STM".JOURNAL OF PHYSICAL CHEMISTRY B 107.47(2003):13111-13116. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。