Synthesis of new ruthenium(II) bipyridyl complexes and studies on their photophysical and photoelectrochemical properties
文献类型：期刊论文
| 作者 | Song, LQ; Xie, PH; Wang, XS; Hou, YJ; Zhang, BW; Cao, Y; Li, WY; Zhang, JB; Xiao, XR; Lin, Y |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2003-06-01 |
| 卷号 | 21期号:6页码:644-649 |
| 关键词 | Ruthenium Complex Photophysical Property Solvatochromic Effect |
| ISSN号 | 1001-604X |
| 英文摘要 | Two new mixed-ligand ruthenium (II) complexes, Ru(dcbpy)(LL) (NCS)(2) [where dcbpy = 4, 4'-dicarboxyl-2, 2'-bipyridine, LL = 4,4'-bis(N-methyl-anilinomethyl)-2,2'-bipyridine (1) or 4-methyl-4'-N-methyl-anilinomethyl-2,2'-bipyridine (2)], were synthesized, and the photophysical properties of these complexes were studied. The metal-to-ligand charge transfer (MLCT) transitions of these complexes exhibited solvatochromic effect due to the existence of NCS ligands. The MLCT energies also strongly depend on the pH values of the solutions because of protonation and deprotonation of the carboxyl groups. The pK(a) values of the ground state, 4.0 for 1 and 3.8 for 2, were obtained from the titration curves. The photoelectrochemical properties of 1 and 2 as sensitizers in sandwich-type solar cells have been studied. Complex 1 exhibited better photoelectrochemical behavior than complex 2 as expected. It was proved that the design of mixed-ligand complex by introducing electron donating group in one of the ligands should be a promising approach. |
| 语种 | 英语 |
| WOS记录号 | WOS:000188291800012 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80267]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Song, LQ |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, LQ,Xie, PH,Wang, XS,et al. Synthesis of new ruthenium(II) bipyridyl complexes and studies on their photophysical and photoelectrochemical properties[J]. CHINESE JOURNAL OF CHEMISTRY,2003,21(6):644-649. |
| APA | Song, LQ.,Xie, PH.,Wang, XS.,Hou, YJ.,Zhang, BW.,...&Lin, Y.(2003).Synthesis of new ruthenium(II) bipyridyl complexes and studies on their photophysical and photoelectrochemical properties.CHINESE JOURNAL OF CHEMISTRY,21(6),644-649. |
| MLA | Song, LQ,et al."Synthesis of new ruthenium(II) bipyridyl complexes and studies on their photophysical and photoelectrochemical properties".CHINESE JOURNAL OF CHEMISTRY 21.6(2003):644-649. |
入库方式： OAI收割
来源：化学研究所
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