Synthesis, crystal structure and electrical conductivity of (bmim)[Pd(dmit)(2))](2) (bmim=1-butyl-3-methylimidazolium, dmit=1,3-dithiol-2-thiol-2-thione-4,5-dithiolate)
文献类型：期刊论文
| 作者 | Jia, CY; Zhang, DQ; Xu, W; Shao, XF; Zhu, DB |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 2003-04-04 |
| 卷号 | 137期号:1-3页码:1345-1346 |
| 关键词 | Organic Conductor Electrocrystalization |
| ISSN号 | 0379-6779 |
| DOI | 10.1016/S0379-6779(02)01085-8 |
| 英文摘要 | The synthesis, structural characterization, and electrical conductivity studies of charge-transfer compound (bmim)[Pd(dmit)(2)](2) was described. This compound was obtained as small needles by electrocrystalization of (bmim)(2)[Pd(dmit)(2)]. Crystallographic parmeters for C20H18N2S20Pd2: monoclinic system; space group: C2/c ; a = 6.3718 (13), b = 14.543 (3), c = 36.339 (7) Angstrom; a = 90, beta = 92.04 (3), gamma = 90; Z = 4, R = 0.0785 (I>2 degrees a (I)). The room temperature conductivity of this salt is 1.2 S . cm(-1), and it shows metallic conducting state in the temperature range of 287-245 K. |
| 语种 | 英语 |
| WOS记录号 | WOS:000182533900217 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80467]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, DQ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, CY,Zhang, DQ,Xu, W,et al. Synthesis, crystal structure and electrical conductivity of (bmim)[Pd(dmit)(2))](2) (bmim=1-butyl-3-methylimidazolium, dmit=1,3-dithiol-2-thiol-2-thione-4,5-dithiolate)[J]. SYNTHETIC METALS,2003,137(1-3):1345-1346. |
| APA | Jia, CY,Zhang, DQ,Xu, W,Shao, XF,&Zhu, DB.(2003).Synthesis, crystal structure and electrical conductivity of (bmim)[Pd(dmit)(2))](2) (bmim=1-butyl-3-methylimidazolium, dmit=1,3-dithiol-2-thiol-2-thione-4,5-dithiolate).SYNTHETIC METALS,137(1-3),1345-1346. |
| MLA | Jia, CY,et al."Synthesis, crystal structure and electrical conductivity of (bmim)[Pd(dmit)(2))](2) (bmim=1-butyl-3-methylimidazolium, dmit=1,3-dithiol-2-thiol-2-thione-4,5-dithiolate)".SYNTHETIC METALS 137.1-3(2003):1345-1346. |
入库方式： OAI收割
来源：化学研究所
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