Dendritic BINAP based system for asymmetric hydrogenation of simple aryl ketones
文献类型：期刊论文
| 作者 | Deng, GJ; Fan, QH; Chen, XM; Liu, GH |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2003-02-17 |
| 卷号 | 193期号:1-2页码:21-25 |
| 关键词 | Asymmetric Hydrogenation Dendritic Catalyst Binap Dpen Chiral Secondary Alcohol |
| ISSN号 | 1381-1169 |
| 英文摘要 | A series of dendritic BINAP-Ru/chiral diamine catalysts were developed for asymmetric hydrogenation of various simple aryl ketones. The resulting catalytic system showed very attractive due to very good catalytic activity and enantioselectivity as well as facile catalyst recycling. In the case of 1-acetonaphthone and 2'-methyl-acetophenone, interesting e.e. value up to 95% was observed which are comparable to the enantioselectivity reported by Noyori under similar conditions and higher than that of the heterogeneous poly(BINAP)-Ru catalyst reported by Pu and co-workers [Tetrahedron Lett. 41 (2000) 1681]. (C) 2002 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000181527300003 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80485]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, QH |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Nankai Univ, State Key Lab Elemental Organ Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, GJ,Fan, QH,Chen, XM,et al. Dendritic BINAP based system for asymmetric hydrogenation of simple aryl ketones[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2003,193(1-2):21-25. |
| APA | Deng, GJ,Fan, QH,Chen, XM,&Liu, GH.(2003).Dendritic BINAP based system for asymmetric hydrogenation of simple aryl ketones.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,193(1-2),21-25. |
| MLA | Deng, GJ,et al."Dendritic BINAP based system for asymmetric hydrogenation of simple aryl ketones".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 193.1-2(2003):21-25. |
入库方式： OAI收割
来源：化学研究所
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