Synthesis of poly(epsilon-caprolactone)-b-poly(gamma-benzyl-L-glutamic acid) block copolymer using amino organic calcium catalyst
文献类型：期刊论文
| 作者 | Rong, GZ; Deng, MX; Deng, C; Tang, ZH; Piao, LH; Chen, XS; Jing, XB |
| 刊名 | BIOMACROMOLECULES
 |
| 出版日期 | 2003-11-01 |
| 卷号 | 4期号:6页码:1800-1804 |
| ISSN号 | 1525-7797 |
| DOI | 10.1021/bm034208z |
| 英文摘要 | A biodegradable two block copolymer, poly(epsilon-caprolactone)-b- poly(gamma-benzyl-L-glutamic acid) (PCL-PBLG) was synthesized successfully by ring-opening polymerization of N-carboxyanhydride of gamma-benzyl-L-glutamate (BLG-NCA) with aminophenyl-terminated PCL as a macroinitiator. The aminophenethoxyl-terminated PCL was prepared via hydrogenation of a 4-nitrophenethoxyl-teminated PCL, which was novelly obtained from the polymerization of c-caprolactone (CL) initiated by amino calcium 4-nitrobenzoxide. The structures of the block copolymer and its precursors from the initial step of PCL were confirmed and investigated by H-1 NMR, FT-IR, GPC, and FT-ICRMS analyses and DSC measurements. |
| 语种 | 英语 |
| WOS记录号 | WOS:000186729700044 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80567]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, XS |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Rong, GZ,Deng, MX,Deng, C,et al. Synthesis of poly(epsilon-caprolactone)-b-poly(gamma-benzyl-L-glutamic acid) block copolymer using amino organic calcium catalyst[J]. BIOMACROMOLECULES,2003,4(6):1800-1804. |
| APA | Rong, GZ.,Deng, MX.,Deng, C.,Tang, ZH.,Piao, LH.,...&Jing, XB.(2003).Synthesis of poly(epsilon-caprolactone)-b-poly(gamma-benzyl-L-glutamic acid) block copolymer using amino organic calcium catalyst.BIOMACROMOLECULES,4(6),1800-1804. |
| MLA | Rong, GZ,et al."Synthesis of poly(epsilon-caprolactone)-b-poly(gamma-benzyl-L-glutamic acid) block copolymer using amino organic calcium catalyst".BIOMACROMOLECULES 4.6(2003):1800-1804. |
入库方式： OAI收割
来源：化学研究所
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