Hydrothermal synthesis and crystal structure of a new alpha-Keggin unit-supported cobalt bipyridyl complex: [Co(2,2 '-bipy)(3)](1.5)[SiW12O40Co(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O
文献类型：期刊论文
| 作者 | Liu, CM; Huang, YH; Zhang, DQ; Jiang, FC; Zhu, DB |
| 刊名 | JOURNAL OF COORDINATION CHEMISTRY
 |
| 出版日期 | 2003-07-20 |
| 卷号 | 56期号:11页码:953-960 |
| 关键词 | Hydrothermal Synthesis Cobalt(Ii) Cluster Complex Crystal Structure Polyoxoanion Complex Keggin Ion |
| ISSN号 | 0095-8972 |
| DOI | 10.1080/0095897031000135342 |
| 英文摘要 | A new alpha-Keggin unit-supported transition metal complex [Co(2,2'-bipy)(3)](1.5)[SiW12O40Co(2,2'-bipy)(2)(H2O)].0.5H(2)O has been hydrothermally synthesized and characterized by X-ray crystallography, showing that [Co(2,2'-bipy)(2)(H2O)](2+) units are covalently bonded to the alpha-Keggin cluster [(SiWW11O50)-W-V-O-VI](5-). Intermolecular hydrogen bonding interactions and short O ... O contacts force the structure into an interesting one-dimensional suprarmolecular array. Crystals are monoclinic space group C2/c, with a = 46.676(9), b = 14.348(3), c = 26.010(5) Angstrom, beta = 90.33(3)degrees, V = 17419(6) Angstrom(3), Z = 8. |
| 语种 | 英语 |
| WOS记录号 | WOS:000185480500004 |
| 出版者 | TAYLOR & FRANCIS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80637]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, CM |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China 2.Jiangxi Normal Univ, Dept Chem, Nanchang 210027, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CM,Huang, YH,Zhang, DQ,et al. Hydrothermal synthesis and crystal structure of a new alpha-Keggin unit-supported cobalt bipyridyl complex: [Co(2,2 '-bipy)(3)](1.5)[SiW12O40Co(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O[J]. JOURNAL OF COORDINATION CHEMISTRY,2003,56(11):953-960. |
| APA | Liu, CM,Huang, YH,Zhang, DQ,Jiang, FC,&Zhu, DB.(2003).Hydrothermal synthesis and crystal structure of a new alpha-Keggin unit-supported cobalt bipyridyl complex: [Co(2,2 '-bipy)(3)](1.5)[SiW12O40Co(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O.JOURNAL OF COORDINATION CHEMISTRY,56(11),953-960. |
| MLA | Liu, CM,et al."Hydrothermal synthesis and crystal structure of a new alpha-Keggin unit-supported cobalt bipyridyl complex: [Co(2,2 '-bipy)(3)](1.5)[SiW12O40Co(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O".JOURNAL OF COORDINATION CHEMISTRY 56.11(2003):953-960. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。