Synthesis and characterization of poly(diethylsiloxane) and its copolymers with different diorganosiloxane units
文献类型：期刊论文
| 作者 | Liu, LH; Yang, SY; Zhang, ZJ; Wang, Q; Xie, ZM |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2003-09-01 |
| 卷号 | 41期号:17页码:2722-2730 |
| 关键词 | Poly(Diethylsiloxane) Copolymers Equilibrium Polymerization Noncrystalline Polymers Glass Transition |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.10822 |
| 英文摘要 | Poly(diethylsiloxane) and its copolymers with various kinds of R1R2SiO (R-1 = R-2 = methyl or phenyl, or R-1 = methyl and R-2 = phenyl) units have been prepared by the equilibrium polymerization of cyclosiloxanes. All the polymers have been characterized by H-1 and Si-29 NMR, gel permeation chromatography, differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA) measurements. The results indicate that a random distribution of different units has been obtained in the structures of copolymers containing 50 mol % diethylsiloxane units content. DSC and DMA show that the presence of 2.5 mol % diphenylsiloxane units or 5.0 mol % methylphenylsiloxane units in the copolymer can disrupt the crystallinity and lead to noncrystalline copolymers with low glass-transition temperatures (ranging from -133 to -137 degreesC according to DSC). (C) 2003 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000184650000011 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80663]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xie, ZM |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, LH,Yang, SY,Zhang, ZJ,et al. Synthesis and characterization of poly(diethylsiloxane) and its copolymers with different diorganosiloxane units[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2003,41(17):2722-2730. |
| APA | Liu, LH,Yang, SY,Zhang, ZJ,Wang, Q,&Xie, ZM.(2003).Synthesis and characterization of poly(diethylsiloxane) and its copolymers with different diorganosiloxane units.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,41(17),2722-2730. |
| MLA | Liu, LH,et al."Synthesis and characterization of poly(diethylsiloxane) and its copolymers with different diorganosiloxane units".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 41.17(2003):2722-2730. |
入库方式： OAI收割
来源：化学研究所
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