Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex
文献类型：期刊论文
| 作者 | Miao, JH; Yang, JH; Chen, LY; Huang, MY; Jiang, YY |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2003-10-01 |
| 卷号 | 14期号:10页码:1008-1011 |
| 关键词 | Wool-osmium Tetroxide Asymmetric Dihydroxylation Allylamine |
| ISSN号 | 1001-8417 |
| 英文摘要 | A new chiral polymer-metal complex, wool-osmium tetroxide(wool-OsO4) complex was prepared by a very simple method. This complex was found to be able to catalyze the asymmetric dihydroxylation of allylamine to get (R)-(+)-3-amino-1, 2-propanediol. The experimental results showed that OsO4 content in the complex, reaction time, allylamine/OsO4 molar ratio all have great effects on the chemical and optical yields of product. Additionally, wool-OsO4 complex catalyst could be reused without remarkable change in optical catalytic activity. |
| 语种 | 英语 |
| WOS记录号 | WOS:000185983600007 |
| 出版者 | CHINESE CHEMICAL SOCIETY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80703]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Miao, JH |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Peoples R China 2.Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Miao, JH,Yang, JH,Chen, LY,et al. Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex[J]. CHINESE CHEMICAL LETTERS,2003,14(10):1008-1011. |
| APA | Miao, JH,Yang, JH,Chen, LY,Huang, MY,&Jiang, YY.(2003).Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex.CHINESE CHEMICAL LETTERS,14(10),1008-1011. |
| MLA | Miao, JH,et al."Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex".CHINESE CHEMICAL LETTERS 14.10(2003):1008-1011. |
入库方式： OAI收割
来源：化学研究所
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