Elementary reaction allyl radical with oxygen
文献类型：期刊论文
| 作者 | Dong, F; Kong, FA |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2003-07-01 |
| 卷号 | 48期号:13页码:1334-1337 |
| 关键词 | Tr-ftir Allyl Radical Elementary Reaction Radical Combustion Reaction |
| ISSN号 | 1001-6538 |
| DOI | 10.1360/02wb0247 |
| 英文摘要 | The elementary reaction between allyl radical with oxygen molecule was experimentally investigated. The allyl radical was produced via laser photolysis of C3H5Br in gaseous phase. Nascent vibrational excited products HCO, CO2, CH3CHO and HCOOH were recorded by the time-resolved Fourier transform infrared spectroscopy. The product channels of C2H5+CO2, CH3CHO+HCO, and HCOOH + C2H3 have been identified. The vibrational populations of product CO2 are obtained by spectral simulation. A mechanism forming a series of three-membered ring-structure intermediates is suggested. |
| 语种 | 英语 |
| WOS记录号 | WOS:000184463200012 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80739]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Kong, FA |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Div, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, F,Kong, FA. Elementary reaction allyl radical with oxygen[J]. CHINESE SCIENCE BULLETIN,2003,48(13):1334-1337. |
| APA | Dong, F,&Kong, FA.(2003).Elementary reaction allyl radical with oxygen.CHINESE SCIENCE BULLETIN,48(13),1334-1337. |
| MLA | Dong, F,et al."Elementary reaction allyl radical with oxygen".CHINESE SCIENCE BULLETIN 48.13(2003):1334-1337. |
入库方式： OAI收割
来源：化学研究所
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