Surface chemical and morphological properties of a blend containing semi-crystalline and amorphous polymers studied with ToF-SIMS, XPS and AFM
文献类型：期刊论文
| 作者 | Lei, YG; Cheung, ZL; Ng, KM; Li, L; Weng, LT; Chan, CM |
| 刊名 | POLYMER
 |
| 出版日期 | 2003-06-01 |
| 卷号 | 44期号:14页码:3883-3890 |
| 关键词 | Semi-crystalline Polymer Blend Surface Morphology And Chemical Composition Surface Segregation |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/S0032-3861(03)000328-8 |
| 英文摘要 | The polymers BA-C8 and 6FBA-C8 were obtained by condensation polymerization of 1,8-dibromo-octane with bisphenol A and 4,4'-(hexafluoroisopropylidene)diphenol, respectively. A blend (BA-C8/6FBA-C8 (80/20)) containing 80 wt% of BA-C8 and 20 wt% 6FBA-C8 was prepared. Only one glass transition temperature was detected using a differential scanning calorimeter, suggesting that the blend is miscible. The surface chemical and morphological properties of the blend were studied as BA-C8 crystallized using atomic force microscopy, X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry and contact angle measurements. The results of the surface analyses showed that the surface of the blend was found to be enriched in the 6FBA-C8 polymer, especially at the crystalline regions. The crystalline regions were found to be raised above the amorphous regions. Surface segregation and crystallization were the two main factors that contributed to the changes in the chemical composition and morphology of the surface. (C) 2003 Elsevier Science Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000183596800015 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80791]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chan, CM |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China 2.Hong Kong Univ Sci & Technol, Dept Chem Engn, Hong Kong, Hong Kong, Peoples R China 3.Hong Kong Univ Sci & Technol, Adv Engn Mat Facil, Hong Kong, Hong Kong, Peoples R China 4.Hong Kong Univ Sci & Technol, Mat Characterizat & Preparat Facil, Hong Kong, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lei, YG,Cheung, ZL,Ng, KM,et al. Surface chemical and morphological properties of a blend containing semi-crystalline and amorphous polymers studied with ToF-SIMS, XPS and AFM[J]. POLYMER,2003,44(14):3883-3890. |
| APA | Lei, YG,Cheung, ZL,Ng, KM,Li, L,Weng, LT,&Chan, CM.(2003).Surface chemical and morphological properties of a blend containing semi-crystalline and amorphous polymers studied with ToF-SIMS, XPS and AFM.POLYMER,44(14),3883-3890. |
| MLA | Lei, YG,et al."Surface chemical and morphological properties of a blend containing semi-crystalline and amorphous polymers studied with ToF-SIMS, XPS and AFM".POLYMER 44.14(2003):3883-3890. |
入库方式： OAI收割
来源：化学研究所
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