中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of chiral binaphthyl crown ethers and their use in anionic polymerization of methyl methacrylate as initiator ligands

文献类型:期刊论文

作者Liu, HW; Chen, CF; Xi, F
刊名CHINESE JOURNAL OF POLYMER SCIENCE
出版日期2003-12-01
卷号22期号:1页码:63-68
关键词Chiral Binaphthyl Crown Ether Mma Anionic Polymerization
ISSN号0256-7679
英文摘要Some chiral binaphthyl crown ethers were synthesized. The anionic polymerization of methyl methacrylate (MMA) was carried out in the presence of t-BuOK, Ph2CHK or Ph2CHNa (RM), and RM coordination initiator by using chiral binaphthyl crown ethers as ligands, respectively. The results showed that in the former case the PMMA obtained has mainly isotactic structure but without optical activity, while in the later case the PMMA produced predominately has syndiotactic structure also without optical activity.
语种英语
WOS记录号WOS:000188355900009
出版者SPRINGER-VERLAG HEIDELBERG
源URL[http://ir.iccas.ac.cn/handle/121111/80893]  
专题中国科学院化学研究所
通讯作者Xi, F
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Liu, HW,Chen, CF,Xi, F. Synthesis of chiral binaphthyl crown ethers and their use in anionic polymerization of methyl methacrylate as initiator ligands[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2003,22(1):63-68.
APA Liu, HW,Chen, CF,&Xi, F.(2003).Synthesis of chiral binaphthyl crown ethers and their use in anionic polymerization of methyl methacrylate as initiator ligands.CHINESE JOURNAL OF POLYMER SCIENCE,22(1),63-68.
MLA Liu, HW,et al."Synthesis of chiral binaphthyl crown ethers and their use in anionic polymerization of methyl methacrylate as initiator ligands".CHINESE JOURNAL OF POLYMER SCIENCE 22.1(2003):63-68.

入库方式: OAI收割

来源:化学研究所

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