Hydration of alkenes catalyzed by wool-palladium-iron complex
文献类型：期刊论文
| 作者 | Jia, B; Yang, X; Huang, MY; Jiang, YY |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2003 |
| 卷号 | 57期号:2-3页码:163-168 |
| 关键词 | Biopolymer Wool-palladium-iron Complex Catalyst Hydration Alkenes Alcohols |
| ISSN号 | 1381-5148 |
| DOI | 10.1016/j.reactfunctpolym.2003.08.006 |
| 英文摘要 | A new biopolymer-metal complex, wool-supported palladium-iron complex (wool-Pd-Fe), has been prepared and found to be a highly active catalyst for hydration of some alkenes to corresponding alcohols, such as allyl bromide to 1-bromo-2-propanol, allyl chloride to 1-chloro-2-propanol, allylamine to 1-amino-2-propanol, acrylonitrile to lactonitrile and cyclohexene to cyclohexanol in 95.0%, 87.5%, 90.6%, 75.3% and 98.2% yield, respectively, in the presence of water, butyl ether and phenol at 95 degreesC under 1 atm N-2. The yield was greatly affected by the Pd/Fe molar ratio in wool-Pd-Fe complex catalyst. And this catalyst was very stable and could be reused several times without remarkable change in the catalytic activity. (C) 2003 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000187666500010 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/80975]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jia, B |
| 作者单位 | Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, B,Yang, X,Huang, MY,et al. Hydration of alkenes catalyzed by wool-palladium-iron complex[J]. REACTIVE & FUNCTIONAL POLYMERS,2003,57(2-3):163-168. |
| APA | Jia, B,Yang, X,Huang, MY,&Jiang, YY.(2003).Hydration of alkenes catalyzed by wool-palladium-iron complex.REACTIVE & FUNCTIONAL POLYMERS,57(2-3),163-168. |
| MLA | Jia, B,et al."Hydration of alkenes catalyzed by wool-palladium-iron complex".REACTIVE & FUNCTIONAL POLYMERS 57.2-3(2003):163-168. |
入库方式： OAI收割
来源：化学研究所
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