Electrochemical properties of methanofullerenes
文献类型：期刊论文
| 作者 | Ning, B; Fan, LZ; Zheng, LP; Cao, Y; Guo, ZX |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2003-10-01 |
| 卷号 | 19期号:10页码:917-921 |
| 关键词 | Fullerene Methanofullerene Cyclic Voltammetry(Cv) Electrochemical Properties Isomerization |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB20031007 |
| 英文摘要 | 11 methanofullerenes have been investigated using cyclic voltammetry(CV) systematically and comparatively. The influence of the nature of groups introduced and chain length of substituents on the electron-accepting ability of methanofullerenes was observed. It was found that introducing electron-donating groups, such as alkyls, weaken the electron-accepting ability of C-60 and make its first reduction wave shifted to more negative position. Introducing electron-withdrawing groups, such as carboxylic ester groups, compensate part of negative shift of the reduction wave due to the effect of the saturation of a fullerene double bond. It was also found that increasing the chain length of substituents would not obviously change the electron-accepting ability of C-60. Furthermore, the split of reduction peaks of some methanofullerenes induced by electrochemical isomerization was explained. |
| 语种 | 英语 |
| WOS记录号 | WOS:000186238300006 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81007]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, LZ |
| 作者单位 | 1.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China 2.S China Univ Technol, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ning, B,Fan, LZ,Zheng, LP,et al. Electrochemical properties of methanofullerenes[J]. ACTA PHYSICO-CHIMICA SINICA,2003,19(10):917-921. |
| APA | Ning, B,Fan, LZ,Zheng, LP,Cao, Y,&Guo, ZX.(2003).Electrochemical properties of methanofullerenes.ACTA PHYSICO-CHIMICA SINICA,19(10),917-921. |
| MLA | Ning, B,et al."Electrochemical properties of methanofullerenes".ACTA PHYSICO-CHIMICA SINICA 19.10(2003):917-921. |
入库方式： OAI收割
来源：化学研究所
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