Hydrogenation of nitrobenzene, cyclohexanone and octene catalyzed by silica-supported starch-L-glutamic acid-Fe complex
文献类型：期刊论文
| 作者 | Liu, HW; Huang, K; Mi, JD; Jia, Y; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2003-03-01 |
| 卷号 | 14期号:3-5页码:355-359 |
| 关键词 | Starch Glutamic Acid Fe Complex Catalyst Hydrogenation Nitrobenzene |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.320 |
| 英文摘要 | A new polymer-base metal complex, silica-supported starch-L-glutamic acid-Fe complex (SiO2-ST-Glu-Fe) has been prepared by a simple method. Starch was reacted with L-glutamic acid in the presence of silica to give a ligand SiO2-ST-Glu, then this was reacted with FeCl3.6H(2)O to form the Fe complex (SiO2-ST-Glu-Fe). The complex has been found to be able to catalyze the hydrogenation of nitrobenzene to give aniline in 100% yield, cyclohexanone to give cyclohexanol in 93% yield and octene to give octane in 84% yield at 45degreesC and under atmospheric pressure. Experimental data show that the catalyst was very stable and could be reused without any noticeable change in its catalytic activity. Copyright (C) 2003 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000182654500032 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81077]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HW |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, HW,Huang, K,Mi, JD,et al. Hydrogenation of nitrobenzene, cyclohexanone and octene catalyzed by silica-supported starch-L-glutamic acid-Fe complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2003,14(3-5):355-359. |
| APA | Liu, HW,Huang, K,Mi, JD,Jia, Y,Huang, MY,&Jiang, YY.(2003).Hydrogenation of nitrobenzene, cyclohexanone and octene catalyzed by silica-supported starch-L-glutamic acid-Fe complex.POLYMERS FOR ADVANCED TECHNOLOGIES,14(3-5),355-359. |
| MLA | Liu, HW,et al."Hydrogenation of nitrobenzene, cyclohexanone and octene catalyzed by silica-supported starch-L-glutamic acid-Fe complex".POLYMERS FOR ADVANCED TECHNOLOGIES 14.3-5(2003):355-359. |
入库方式： OAI收割
来源：化学研究所
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