中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene

文献类型:期刊论文

作者Xue, H; Xu, YA; Ding, JY; Gao, LX; Ding, MX
刊名POLYMER INTERNATIONAL
出版日期2003-09-01
卷号52期号:9页码:1423-1427
关键词Atom Transfer Radical Polymerization Optically Active Polymer Specific Rotation 1 1 '-binaphthyl Moiety
ISSN号0959-8103
DOI10.1002/pi.1236
英文摘要Atom transfer radical polymerization (ATPP) of (R)-2-methacryloyloxy-2'-methoxy-1,1'-binaphthalene ((R)-MAMBN) mediated by different amine ligands, copper(l) chloride and ethyl 2-bromopropionate in different solvents, and reverse ATRP of (R)-MAMBN were studied. It was shown that optically active polymers were obtained, with poor control of the molecular weights, and low polydispersities. Specific rotation of the polymers increased with increasing molecular weights. By comparison with (R)-MAMBN, poly((R)-MAMBN)s exhibits higher specific rotation and a positive Cotton effect. (C) 2003 Society of Chemical Industry.
语种英语
WOS记录号WOS:000185206400004
出版者JOHN WILEY & SONS LTD
源URL[http://ir.iccas.ac.cn/handle/121111/81113]  
专题中国科学院化学研究所
通讯作者Ding, MX
作者单位Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Xue, H,Xu, YA,Ding, JY,et al. Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene[J]. POLYMER INTERNATIONAL,2003,52(9):1423-1427.
APA Xue, H,Xu, YA,Ding, JY,Gao, LX,&Ding, MX.(2003).Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene.POLYMER INTERNATIONAL,52(9),1423-1427.
MLA Xue, H,et al."Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene".POLYMER INTERNATIONAL 52.9(2003):1423-1427.

入库方式: OAI收割

来源:化学研究所

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