A thermally stable chromophore with multi-intramolecular charge-transfer and its poled polymer
文献类型：期刊论文
| 作者 | Anjun, Q; Hu, K; Shaojun, L; Cheng, Y |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 2003-04-04 |
| 卷号 | 137期号:1-3页码:1517-1518 |
| 关键词 | Guest-host Polymer In Situ Shg Measurement Thermal Stability Multi-intramolecular Charge Transfer |
| ISSN号 | 0379-6779 |
| DOI | 10.1016/S0379-6779(02)01216-X |
| 英文摘要 | A new second-order nonlinear optical (NLO) multi-intramolecular charge-transler chromophore 2.3-bis (4-aminophenyl)-5,6-dicyanopyrazine (DAPDCP) has been desioned and synthesized successfully. It shows that the maximum absorption wavelength lambda(max) of UV/Vis spectrum in 1,4-dioxane is 423 nm and the melting point is above 300degreesC. The doped film of it in PMMA was prepared and poled by corona poling with increasing temperature step by step (5degreesC/min). The second-order nonlinear optical coefficient d(33) is deduced to be 27.2pm/V by the in-situ SHG measurements. The depoling experiments showed that the on-set temperature of the decay of orientation order is 105degreesC which is higoher than that of the typical NLO chromophore N-(4-nitro phenyl)-(s)-prolinol (NPP) doped in PMMA. It has demonstrated again that the harmony of thermal stable-nonlinearility-transparent trade-off can be established by using the designed X-type chromophore with multi-intramolecular charge-transter. |
| 语种 | 英语 |
| WOS记录号 | WOS:000182533900295 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81221]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Organ Solids Lab, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Anjun, Q,Hu, K,Shaojun, L,et al. A thermally stable chromophore with multi-intramolecular charge-transfer and its poled polymer[J]. SYNTHETIC METALS,2003,137(1-3):1517-1518. |
| APA | Anjun, Q,Hu, K,Shaojun, L,&Cheng, Y.(2003).A thermally stable chromophore with multi-intramolecular charge-transfer and its poled polymer.SYNTHETIC METALS,137(1-3),1517-1518. |
| MLA | Anjun, Q,et al."A thermally stable chromophore with multi-intramolecular charge-transfer and its poled polymer".SYNTHETIC METALS 137.1-3(2003):1517-1518. |
入库方式： OAI收割
来源：化学研究所
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