Vinyl-polymerization of norbornene catalyzed by bis-[N(substituted methyl)-salicylideneiminato]nickel/MAO system
文献类型：期刊论文
| 作者 | Yang, HJ; Sun, WH; Chang, F; Li, Y |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2003-10-15 |
| 卷号 | 252期号:2页码:261-267 |
| 关键词 | Vinyl-polymerization Polynorbornene Steric Hindrance Amorphous Polymers |
| ISSN号 | 0926-860X |
| DOI | 10.1016/S0926-860X(03)00472-1 |
| 英文摘要 | The bis-[N-(substituted methyl)-salicylideneiminato]nickel/MAO systems were utilized to promote the vinylic homo-polymerization of norbornene. The results displayed that steric hindrance has significant effects on their catalytic activities for polymerization of norbomene. The complex a, bis- [N-(diphenylmethyl)-salicylideneiminato] nickel, is systematically investigated with the catalytic activity up to 4.23 x 10(8) g PNB/(mol Ni h) and the average molecular weight up to 3.26 x 10(6) g/mol. All the polymer samples obtained here are soluble at room temperature in chlorobenzene. No indication of stereoregularity was observed; this was verified by the amorphous morphology of the products. The catalytic activities, yields, molecular weights and molecular weight distributions could be controlled over a wide range via variations of the reaction parameters. (C) 2003 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000186140800005 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81231]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, WH |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, HJ,Sun, WH,Chang, F,et al. Vinyl-polymerization of norbornene catalyzed by bis-[N(substituted methyl)-salicylideneiminato]nickel/MAO system[J]. APPLIED CATALYSIS A-GENERAL,2003,252(2):261-267. |
| APA | Yang, HJ,Sun, WH,Chang, F,&Li, Y.(2003).Vinyl-polymerization of norbornene catalyzed by bis-[N(substituted methyl)-salicylideneiminato]nickel/MAO system.APPLIED CATALYSIS A-GENERAL,252(2),261-267. |
| MLA | Yang, HJ,et al."Vinyl-polymerization of norbornene catalyzed by bis-[N(substituted methyl)-salicylideneiminato]nickel/MAO system".APPLIED CATALYSIS A-GENERAL 252.2(2003):261-267. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。