Chemical chromogenic sensors based on calixarenes: Syntheses and recognition properties for alkylamines
文献类型：期刊论文
| 作者 | Zheng, QY; Chen, CF; Huang, ZT |
| 刊名 | JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
 |
| 出版日期 | 2003-02-01 |
| 卷号 | 45期号:1-2页码:27-34 |
| 关键词 | Calixarene Chromogenic Receptor Molecular Recognition |
| ISSN号 | 0923-0750 |
| 英文摘要 | Nitration of 1,3-distal dialkylated calix[4]arenes was investigated in order to prepare chromogenic sensor compounds. There were three kinds of separable products, which came from the nitration and oxidation of the phenol moieties. The cone conformation of calix[4]arenes containing a quinone structure was first determined. And the effect of the structure of reactants for the nitration and oxidation is also discussed. Dinitrated calix[4]arenes possess recognition ability for the alkylamines, which can be as the chromogenic sensors for determining the alkylamines. The recognition behavior was due to the proton transfer between alkylamine and calix[4]arenes, and the resulting ammonium phenoxide was stabilized by the phenoxide oxygen atom and the carbonyl at the lower rim with hydrogen bonding. |
| 语种 | 英语 |
| WOS记录号 | WOS:000182006000005 |
| 出版者 | KLUWER ACADEMIC PUBL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81265]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, ZT |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, QY,Chen, CF,Huang, ZT. Chemical chromogenic sensors based on calixarenes: Syntheses and recognition properties for alkylamines[J]. JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY,2003,45(1-2):27-34. |
| APA | Zheng, QY,Chen, CF,&Huang, ZT.(2003).Chemical chromogenic sensors based on calixarenes: Syntheses and recognition properties for alkylamines.JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY,45(1-2),27-34. |
| MLA | Zheng, QY,et al."Chemical chromogenic sensors based on calixarenes: Syntheses and recognition properties for alkylamines".JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY 45.1-2(2003):27-34. |
入库方式： OAI收割
来源：化学研究所
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