A new hetero-spin compound derived from 1,4-bis(nitronyl nitroxide)benzene and Mn(II)hexafluoroacetylacetonate for studies on molecular magnetism
文献类型：期刊论文
| 作者 | Zhang, D; Liu, W; Shuai, Z; Hu, H; Xu, W; Zhu, D |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 2003-03-13 |
| 卷号 | 133页码:601-603 |
| 关键词 | Molecular Magnetism Hetero-spin Compound Nitronyl Nitroxide |
| ISSN号 | 0379-6779 |
| 英文摘要 | A new hetero-spin compound 1 derived from 1,4-bis(nitronyl nitroxide) benzene and Mn(II) hexafluoroacetylacetonate [Mn(hfac)(2)] was prepared and characterized. Its crystal structure was determined: monoclinic, P2(1)/n, a = 16.3260(7) Angstrom, b = 13.7080(7) Angstrom, c = 18.396(1) Angstrom, beta = 68.380(5)degrees, V = 3827.3(3) Angstrom(3), Z = 4. The intramolecular spin-spin exchange parameters for Mn(II) ion and nitronyl nitroxide unit (J(12) = -108.3 cm(-1)), two nitronyl nitroxide units (J(23) = -31.0 cm(-1)) as well as the intermolecular spin-spin coupling (zJ' = 4.9 cm(-1)) were deduced based on these magnetic data measured with SQUID. (C) 2002 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000181831400177 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81299]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, D |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, D,Liu, W,Shuai, Z,et al. A new hetero-spin compound derived from 1,4-bis(nitronyl nitroxide)benzene and Mn(II)hexafluoroacetylacetonate for studies on molecular magnetism[J]. SYNTHETIC METALS,2003,133:601-603. |
| APA | Zhang, D,Liu, W,Shuai, Z,Hu, H,Xu, W,&Zhu, D.(2003).A new hetero-spin compound derived from 1,4-bis(nitronyl nitroxide)benzene and Mn(II)hexafluoroacetylacetonate for studies on molecular magnetism.SYNTHETIC METALS,133,601-603. |
| MLA | Zhang, D,et al."A new hetero-spin compound derived from 1,4-bis(nitronyl nitroxide)benzene and Mn(II)hexafluoroacetylacetonate for studies on molecular magnetism".SYNTHETIC METALS 133(2003):601-603. |
入库方式： OAI收割
来源：化学研究所
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