Synthesis and liquid crystal properties of a novel class of oligothiophene derivatives
文献类型：期刊论文
| 作者 | Liu, P; Zhou, XP; Hu, JH; Zhao, QZ; Deng, WJ; Tong, Z; Xu, YH; Wan, MX |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2003-05-01 |
| 卷号 | 61期号:5页码:774-779 |
| 关键词 | Oligothiophene Liquid Crystal Intermolecular Hydrogen Bonding |
| ISSN号 | 0567-7351 |
| 英文摘要 | With the aim of developing new oligothiophene-based liquid crystals involving hydrogen bonding, new terthiophene derivative's containing an alkylamide group, N,N'-dialkyl-5,5"-dibromo-2,2': 5', 2"-terthiophene-4,4"-dicarboxamide (DNC(n)DBr3T, n = 5, 8, 16, 18), were designed and synthesized, and their thermal behaviors were examined. While DNC(n)DBr3T compounds with n 16, 18 were found to form smectic A phase, DNC(5)DBr3T did not form liquid crystal phase. In addition to liquid crystal behavior, crystal polymorphism was also observed for DNC(16)DBr3T. It is shown that the alkyl chain length greatly affects liquid crystal phase formation. The absence of liquid crystallinity in the corresponding ester derivatives suggests that intermolecular hydrogen bonding plays a role in the formation of liquid crystal phase in the DNC(n)DBr3T system. |
| 语种 | 英语 |
| WOS记录号 | WOS:000184075700023 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81329]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, P |
| 作者单位 | 1.S China Univ Technol, Math Sci Res Inst, Guangzhou 510640, Peoples R China 2.S China Univ Technol, Dept Appl Phys, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, P,Zhou, XP,Hu, JH,et al. Synthesis and liquid crystal properties of a novel class of oligothiophene derivatives[J]. ACTA CHIMICA SINICA,2003,61(5):774-779. |
| APA | Liu, P.,Zhou, XP.,Hu, JH.,Zhao, QZ.,Deng, WJ.,...&Wan, MX.(2003).Synthesis and liquid crystal properties of a novel class of oligothiophene derivatives.ACTA CHIMICA SINICA,61(5),774-779. |
| MLA | Liu, P,et al."Synthesis and liquid crystal properties of a novel class of oligothiophene derivatives".ACTA CHIMICA SINICA 61.5(2003):774-779. |
入库方式： OAI收割
来源：化学研究所
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