Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone
文献类型：期刊论文
| 作者 | Xue, L; Li, BY; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2003-03-01 |
| 卷号 | 14期号:3-5页码:282-286 |
| 关键词 | Alginic Acid L-glutamic Acid Pt Complex Catalyst 4-methyl-2-pentanone Asymmetric Hydrogenation |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.307 |
| 英文摘要 | A new chiral polymer-metal complex, silica-supported alginic acid-L-glutamic acid-Pt complex (SiO2-AA-L-Glu-Pt), has been prepared by a very simple method and has been found to be able to catalyze the asymmetric hydrogenation of 4-methyl-2-pentanone to give (R)-(-)-4-methyl-2-pentanol in 90.8% optical yield at 30degreesC and under 1 atm H-2. The product and optical yields were greatly affected by the Pt content in the complex, the solvent, the 4-methyl-2-pentanone/Pt molar ratio and the reaction temperature. The catalyst could be reused several times without any great change in its optical catalytic activity. Copyright (C) 2003 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000182654500019 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81407]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xue, L |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, L,Li, BY,Huang, MY,et al. Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2003,14(3-5):282-286. |
| APA | Xue, L,Li, BY,Huang, MY,&Jiang, YY.(2003).Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone.POLYMERS FOR ADVANCED TECHNOLOGIES,14(3-5),282-286. |
| MLA | Xue, L,et al."Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone".POLYMERS FOR ADVANCED TECHNOLOGIES 14.3-5(2003):282-286. |
入库方式： OAI收割
来源：化学研究所
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