The synthesis of CDA-g-PMMA copolymers through atom transfer radical polymerization
文献类型：期刊论文
| 作者 | Shen, DW; Yong, H |
| 刊名 | POLYMER
 |
| 出版日期 | 2004-09-29 |
| 卷号 | 45期号:21页码:7091-7097 |
| 关键词 | Graft Copolymer Cellulose Diacetate Atom Transfer Radical Polymerization |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2004.08.042 |
| 英文摘要 | Graft copolymer of cellulose diacetate (CDA) and PMMA was synthesized through atom transfer radical polymerization (ATRP). The residual hydroxyl groups on the diacetate cellulose reacted with 2-bromoisobutyryl bromide to yield 2-bromoisobutyryl groups known to be an efficient initiator for ATRP. Then the functional CDA was used as macroinitiator in the ATRP of MMA. The polymerization was carried out in the system of PMDETA/CuBr/1,4-dioxane under 70 degreesC. Kinetic study indicated that the polymerization is first order. Copolymers were characterized by H-1 NMR and GPC. The molecular weight increased without any trace of the macroinitiator, and the polydispersities were low. (C) 2004 Published by Elsevier Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000224213800008 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81541]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yong, H |
| 作者单位 | Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, DW,Yong, H. The synthesis of CDA-g-PMMA copolymers through atom transfer radical polymerization[J]. POLYMER,2004,45(21):7091-7097. |
| APA | Shen, DW,&Yong, H.(2004).The synthesis of CDA-g-PMMA copolymers through atom transfer radical polymerization.POLYMER,45(21),7091-7097. |
| MLA | Shen, DW,et al."The synthesis of CDA-g-PMMA copolymers through atom transfer radical polymerization".POLYMER 45.21(2004):7091-7097. |
入库方式： OAI收割
来源：化学研究所
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