FTIR study of poly(propylene carbonate)/bisphenol A blends
文献类型：期刊论文
| 作者 | Fei, B; Chen, C; Peng, SW; Zhao, XJ; Wang, XH; Dong, LS |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2004-12-01 |
| 卷号 | 53期号:12页码:2092-2098 |
| 关键词 | Poly(Propylene Carbonate) Blends Ftir Degradation |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.1633 |
| 英文摘要 | A systematic investigation by FTIR spectroscopy was undertaken on blends of poly(propylene carbonate) (PPC) and bisphenol A (BPA). It provided direct evidence of the hydrogen bond (H-bond) between BPA O-H groups and PPC C=O groups. Using a curve-fitting method, qualitative as well as quantitative information concerning this H-bond interaction was obtained. The inter-H-bond in PPC/BPA blends was weaker than the self-H-bond in BPA. The absorptivities of the free and the H-bonded C=O groups were nearly equal. The fraction of H-bonded C=O in the blends increased with BPA content and leveled off at a value close to 40%. Finally, FTIR-temperature measurements of pure PPC and a representative blend were reported: by monitoring the peak areas of C=O absorptions, the dissociation of the inter-H-bonds and the thermal degradation of PPC were observed. It revealed that the presence of BPA clearly retarded the thermal degradation of PPC. (C) 2004 Society of Chemical Industry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000225347700027 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81569]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fei, B |
| 作者单位 | Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fei, B,Chen, C,Peng, SW,et al. FTIR study of poly(propylene carbonate)/bisphenol A blends[J]. POLYMER INTERNATIONAL,2004,53(12):2092-2098. |
| APA | Fei, B,Chen, C,Peng, SW,Zhao, XJ,Wang, XH,&Dong, LS.(2004).FTIR study of poly(propylene carbonate)/bisphenol A blends.POLYMER INTERNATIONAL,53(12),2092-2098. |
| MLA | Fei, B,et al."FTIR study of poly(propylene carbonate)/bisphenol A blends".POLYMER INTERNATIONAL 53.12(2004):2092-2098. |
入库方式： OAI收割
来源：化学研究所
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