The reaction of formyl radical with chlorine atom
文献类型:期刊论文
作者 | Qu, ZW; Dong, F; Zhang, QY; Kong, FN |
刊名 | CHEMICAL PHYSICS LETTERS
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出版日期 | 2004-03-11 |
卷号 | 386期号:4-6页码:384-389 |
ISSN号 | 0009-2614 |
DOI | 10.1016/j.cplett.2004.01.051 |
英文摘要 | The radical-radical reaction of formyl radical with chlorine atom has been investigated by the time-resolved infrared emission spectroscopy and by the theoretical calculations at the UB3LYP/6-31++G(d,p) and single-point UCCSD(T)/6-311++G(d,p) levels. The products have been verified as the vibrationally excited CO (upsilonless than or equal to4) and HCl. The reaction is initiated by radical-radical recombination forming an intermediate of formaldehyde chloride, which further dissociates into the products of HCl and CO. (C) 2004 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000220124700030 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/81583] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Kong, FN |
作者单位 | Chinese Acad Sci, Inst Chem, Lab Mol React Dynam, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Qu, ZW,Dong, F,Zhang, QY,et al. The reaction of formyl radical with chlorine atom[J]. CHEMICAL PHYSICS LETTERS,2004,386(4-6):384-389. |
APA | Qu, ZW,Dong, F,Zhang, QY,&Kong, FN.(2004).The reaction of formyl radical with chlorine atom.CHEMICAL PHYSICS LETTERS,386(4-6),384-389. |
MLA | Qu, ZW,et al."The reaction of formyl radical with chlorine atom".CHEMICAL PHYSICS LETTERS 386.4-6(2004):384-389. |
入库方式: OAI收割
来源:化学研究所
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