Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine
文献类型:期刊论文
作者 | Wang, M; Gao, LX; Mai, WP; Xia, AX; Wang, F; Zhang, SB |
刊名 | JOURNAL OF ORGANIC CHEMISTRY
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出版日期 | 2004-04-16 |
卷号 | 69期号:8页码:2874-2876 |
ISSN号 | 0022-3263 |
DOI | 10.1021/jo035719e |
英文摘要 | Chiral quaternary ammonium salts derived from cinchonidine have been applied to catalyze the stereoselective iodolactonizations of trans-5-aryl-4-pentenoic acids leading to a mixture of two regioselectively iodolactonized products with fair to excellent yield (37-98%) and moderate enantioselectivity (exo = 42.0% ee, endo = 31.0% ee) under mild conditions. This work is the first example of asymmetric iodolactonization reaction in the presence of less than a stoichiometric amount of chiral reagent. |
语种 | 英语 |
WOS记录号 | WOS:000220752500035 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/81587] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Gao, LX |
作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, M,Gao, LX,Mai, WP,et al. Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine[J]. JOURNAL OF ORGANIC CHEMISTRY,2004,69(8):2874-2876. |
APA | Wang, M,Gao, LX,Mai, WP,Xia, AX,Wang, F,&Zhang, SB.(2004).Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine.JOURNAL OF ORGANIC CHEMISTRY,69(8),2874-2876. |
MLA | Wang, M,et al."Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine".JOURNAL OF ORGANIC CHEMISTRY 69.8(2004):2874-2876. |
入库方式: OAI收割
来源:化学研究所
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