Asymmetric hydrogenation of ketones catalyzed by silica-supported chitosan-iron-nickel complex
文献类型：期刊论文
| 作者 | Zhou, DQ; Zhou, DJ; Cui, XH; Wang, FM; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2004-06-01 |
| 卷号 | 15期号:6页码:350-354 |
| 关键词 | Asymmetric Hydrogenation Silica-supported Chitosar-iron-nickel Catalyst Propiophenone Acetophenone 1-phenyl-1propanol 1-phenyl Ethanol |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.442 |
| 英文摘要 | A new silica-supported biopolymer-metal complex, silica-supported chitosan-iron-nickel complex was prepared by a very simple method. This complex catalyst can be used as a catalyst in the asymmetric hydrogenation of propiophenone to (R)-(+)-1-phenyl-1-propanol and acetophenone to (R)(+)-1-phenyl ethanol in 91.7 and 77.7% optical yields, respectively, at 110 C and under 70 kg/cm(2) pressure. The catalyst could be reused several times without any remarkable change in the catalytic activity. Copyright (C) 2004 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000221802200011 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81661]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhou, DJ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, DQ,Zhou, DJ,Cui, XH,et al. Asymmetric hydrogenation of ketones catalyzed by silica-supported chitosan-iron-nickel complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2004,15(6):350-354. |
| APA | Zhou, DQ,Zhou, DJ,Cui, XH,Wang, FM,Huang, MY,&Jiang, YY.(2004).Asymmetric hydrogenation of ketones catalyzed by silica-supported chitosan-iron-nickel complex.POLYMERS FOR ADVANCED TECHNOLOGIES,15(6),350-354. |
| MLA | Zhou, DQ,et al."Asymmetric hydrogenation of ketones catalyzed by silica-supported chitosan-iron-nickel complex".POLYMERS FOR ADVANCED TECHNOLOGIES 15.6(2004):350-354. |
入库方式： OAI收割
来源：化学研究所
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