Preparation of novel macromonomers and study of their polymerization
文献类型：期刊论文
| 作者 | Deng, GH; Chen, YM |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2004-08-01 |
| 卷号 | 42期号:15页码:3887-3896 |
| 关键词 | Atom Transfer Radical Polymerization (Atrp) Graft Copolymers Macromonomers Polymer Brush |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.20241 |
| 英文摘要 | Novel macromonomers of polystyrene and poly(tert-butyl acrylate) containing a methacryloyl group as a polymerizable unit and two chains of the same length were prepared in two steps: the synthesis of the precursors through the atom transfer radical polymerization of styrene and tert-butyl acrylate initiated by 1-hydroxymethyl-1,1-di[(2-bromoisobutyryloxy)methyl] ethane and the esterification of the hydroxyl group in the precursors with methacryloyl chloride. The molecular weight and polydispersity of the macromonomers were controllable because of the living nature of the atom transfer radical polymerization. Gel permeation chromatography, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and hydrolysis confirmed the structure of the novel macromonomers. The homopolymerization and copolymerization of the macromonomers were investigated to prepare branched copolymers in which two chains were grafted from every repeating unit. (C) 2004 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000222708700026 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81665]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, YM |
| 作者单位 | Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, GH,Chen, YM. Preparation of novel macromonomers and study of their polymerization[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2004,42(15):3887-3896. |
| APA | Deng, GH,&Chen, YM.(2004).Preparation of novel macromonomers and study of their polymerization.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,42(15),3887-3896. |
| MLA | Deng, GH,et al."Preparation of novel macromonomers and study of their polymerization".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 42.15(2004):3887-3896. |
入库方式： OAI收割
来源：化学研究所
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