中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Influence of additives on the crystal structure and melting behavior of poly(ethylene-2,6-naphthalene dicarboxylate)

文献类型:期刊论文

作者Gao, X; Liu, RG; Yu, Y; Jin, M; Bus, HS
刊名JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
出版日期2004-01-15
卷号42期号:2页码:296-301
关键词Crystal Modification Melting Behavior Additives Nucleating Agent Nucleating Promoter Poly(Ethylene-2 6-naphthalene Dicarboxylate)
ISSN号0887-6266
DOI10.1002/polb.10600
英文摘要The influence of additives on the crystal modification and melting behavior of poly(ethylene-2,6-naphthalene dicarboxylate) (PEN) was investigated with wide-angle X-ray diffraction and differential scanning calorimetry (DSC). The addition of a nucleating promoter, Ceraflour 993, had no effect on the crystal modification and melting behavior of PEN crystallized under all chosen experimental conditions. However, the addition of a nucleating agent, sodium benzoate (SB), did affect the crystal modification and melting behavior of PEN when PEN/SB was crystallized at a higher temperature, but not at a lower temperature. A mixture of alpha and beta modifications of PEN was obtained, and an overlapped dual melting peak was observed in DSC curves when PEN was crystallized at a higher temperature in the presence of SB, instead of a single crystal form and a single melting peak for the crystallization of pure PEN. (C) 2003 Wiley Periodicals, Inc.
语种英语
WOS记录号WOS:000187730700013
出版者JOHN WILEY & SONS INC
源URL[http://ir.iccas.ac.cn/handle/121111/81733]  
专题中国科学院化学研究所
通讯作者Bus, HS
作者单位1.Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
2.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Gao, X,Liu, RG,Yu, Y,et al. Influence of additives on the crystal structure and melting behavior of poly(ethylene-2,6-naphthalene dicarboxylate)[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2004,42(2):296-301.
APA Gao, X,Liu, RG,Yu, Y,Jin, M,&Bus, HS.(2004).Influence of additives on the crystal structure and melting behavior of poly(ethylene-2,6-naphthalene dicarboxylate).JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,42(2),296-301.
MLA Gao, X,et al."Influence of additives on the crystal structure and melting behavior of poly(ethylene-2,6-naphthalene dicarboxylate)".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 42.2(2004):296-301.

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来源:化学研究所

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