Oxidation of styrene with molecular oxygen in supercritical CO2
文献类型：期刊论文
| 作者 | Jiang, T; Han, BX; Zhao, GY; Li, ZH; Chang, YH; Gao, HX; Li, JC |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2004-03-01 |
| 卷号 | 15期号:3页码:296-299 |
| 关键词 | Styrene Supercritical Fluids Carbon Dioxide Wacker Oxidation Molecular Oxygen |
| ISSN号 | 1001-8417 |
| 英文摘要 | The oxidation of styrene with molecular oxygen catalyzed by PdCl2+CuCl2 has been investigated in supercritical CO2 with a batch reactor. The oxidative system of styrene contains four components at the beginning and seven components during the reaction. The critical temperature, critical pressure, and critical density at different conversions are determined by using a high-pressure view cell. The effect of phase behavior on the conversion and selectivity were studied. Experimental results showed that the critical parameters of the reaction mixture at fixed initial molar ratio changed with the conversion of reactant. The conversion of styrene reached maximum near the critical density of the reaction mixture. Product selectivity also varied with density of reaction mixture and could be tuned to some degree. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220230500014 |
| 出版者 | CHINESE CHEMICAL SOCIETY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81759]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, BX |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, T,Han, BX,Zhao, GY,et al. Oxidation of styrene with molecular oxygen in supercritical CO2[J]. CHINESE CHEMICAL LETTERS,2004,15(3):296-299. |
| APA | Jiang, T.,Han, BX.,Zhao, GY.,Li, ZH.,Chang, YH.,...&Li, JC.(2004).Oxidation of styrene with molecular oxygen in supercritical CO2.CHINESE CHEMICAL LETTERS,15(3),296-299. |
| MLA | Jiang, T,et al."Oxidation of styrene with molecular oxygen in supercritical CO2".CHINESE CHEMICAL LETTERS 15.3(2004):296-299. |
入库方式： OAI收割
来源：化学研究所
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