Cyclo-depolymerization of several amorphous aromatic polyether sulfone (ketone)s and ring-opening polymerization of the products
文献类型：期刊论文
| 作者 | Wang, HH; Luo, FL; Bo, SQ; Chen, TL |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2004-07-28 |
| 卷号 | 62期号:14页码:1344-1348 |
| 关键词 | Amorphous Polyether Sulfone(Ketone) Cyclo-depolymerization Cyclic Oligomer Cesium Fluoride |
| ISSN号 | 0567-7351 |
| 英文摘要 | Three amorphous aromatic polyether sulfone(ketone)s with different structures underwent a cyclo-depolymerization reaction using CsF as the catalyst in dipolar aprotic solvents such as DMAc and DMF to afford corresponding cyclic oligomer products. The results were confirmed by GPC, HPLC and MALDI-TOF-MS. The yields of phenolphthalein polyether sulfane (PES-C) and phenolphthalein polyether ketone (PEK-C) cyclics reach as high as 86.3% and 87.9% respectively. Relative factors that influence the yields of cyclics were discussed. High molecular weight linear products were regenerated after the ring-opening polymerization of the cyclo-products using potassium phenoxide as initiator. |
| 语种 | 英语 |
| WOS记录号 | WOS:000222935900015 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81817]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, HH |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, HH,Luo, FL,Bo, SQ,et al. Cyclo-depolymerization of several amorphous aromatic polyether sulfone (ketone)s and ring-opening polymerization of the products[J]. ACTA CHIMICA SINICA,2004,62(14):1344-1348. |
| APA | Wang, HH,Luo, FL,Bo, SQ,&Chen, TL.(2004).Cyclo-depolymerization of several amorphous aromatic polyether sulfone (ketone)s and ring-opening polymerization of the products.ACTA CHIMICA SINICA,62(14),1344-1348. |
| MLA | Wang, HH,et al."Cyclo-depolymerization of several amorphous aromatic polyether sulfone (ketone)s and ring-opening polymerization of the products".ACTA CHIMICA SINICA 62.14(2004):1344-1348. |
入库方式： OAI收割
来源：化学研究所
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