Synthesis and chemical properties of conjugated polyacetylenes having pendant fullerene and/or porphyrin units
文献类型：期刊论文
| 作者 | Lu, FS; Xiao, SQ; Li, YL; Liu, HB; Li, HM; Zhuang, JP; Liu, Y; Wang, N; He, XR; Li, XF |
| 刊名 | MACROMOLECULES
 |
| 出版日期 | 2004-10-05 |
| 卷号 | 37期号:20页码:7444-7450 |
| ISSN号 | 0024-9297 |
| DOI | 10.1021/ma0490045 |
| 英文摘要 | Conjugated polyacetylenes having pendant fullerene and/or porphyrin groups were prepared by copolymerization in the presence of [Rh(nbd)Cl](2)-NEt3 in CHCl3. The photochemical and electrochemical properties of the polymers were studied by UV-vis spectroscopy and voltammetry. The photoinduced charge-transfer properties of the monolayer films were also measured by a three-electrode cell technique. More importantly, poly(1a(0.2)-co-5(0.8)) shows a high capacity to form a photoinduced charge-separated state and to produce steady and prompt photocurrent at the irradiation of 21.2 mW cm(-2) white light. We estimate an aerobic IPCE value of 0.15% for a true monolayer coverage of poly(1a(0.2)-co-5(0.8)) at its peak absorption around 440 nm (the maximum of the Soret band). |
| 语种 | 英语 |
| WOS记录号 | WOS:000224197500005 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81839]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, YL |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, FS,Xiao, SQ,Li, YL,et al. Synthesis and chemical properties of conjugated polyacetylenes having pendant fullerene and/or porphyrin units[J]. MACROMOLECULES,2004,37(20):7444-7450. |
| APA | Lu, FS.,Xiao, SQ.,Li, YL.,Liu, HB.,Li, HM.,...&Zhu, DB.(2004).Synthesis and chemical properties of conjugated polyacetylenes having pendant fullerene and/or porphyrin units.MACROMOLECULES,37(20),7444-7450. |
| MLA | Lu, FS,et al."Synthesis and chemical properties of conjugated polyacetylenes having pendant fullerene and/or porphyrin units".MACROMOLECULES 37.20(2004):7444-7450. |
入库方式： OAI收割
来源：化学研究所
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