Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = La, Lu)
文献类型：期刊论文
| 作者 | Cheng, JH; Cui, DM; Chen, WQ; Tang, T; Huang, BT |
| 刊名 | POLYHEDRON
 |
| 出版日期 | 2004-03-25 |
| 卷号 | 23期号:6页码:1075-1080 |
| 关键词 | Tetrahydrofurfurylindenyl Lanthanide Chlorides Crystal Structure Ionic Radius |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2004.01.020 |
| 英文摘要 | Reaction of two equivalents of tetrahydrofurfuryl indenyl lithium with anhydrous lanthanide trichlorides in THF afforded bis(tetrahydrofurfurylindenyl) lanthanide chlorides (C4H7OCH2C9H6)(2)LnCl, Ln=La(l), Pr(2), Lu(3). Complexes I and 3 are characterized by single-crystal analysis. The results of crystal structural determination reveal that they are 9-coordinate monomeric intramolecular complexes with a trans arrangement of both the sidearms and indenyl rings in the solid state. The effects of rare earth ionic radii on the structures Of (C4H7OCH2C9H6)(2)LnCl are discussed. (C) 2004 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220677700024 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81915]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, T |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Changchun Univ Technol, Dept Chem Engn, Changchun 130012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, JH,Cui, DM,Chen, WQ,et al. Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = La, Lu)[J]. POLYHEDRON,2004,23(6):1075-1080. |
| APA | Cheng, JH,Cui, DM,Chen, WQ,Tang, T,&Huang, BT.(2004).Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = La, Lu).POLYHEDRON,23(6),1075-1080. |
| MLA | Cheng, JH,et al."Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = La, Lu)".POLYHEDRON 23.6(2004):1075-1080. |
入库方式： OAI收割
来源：化学研究所
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