Study on the binding ability of mono-6-p-nitrobenzoyl-beta-cyclodextrin with naphthalene derivatives in aqueous solution
文献类型：期刊论文
| 作者 | Wang, YH; Zhu, MZ; Ye, JP; Guo, QX |
| 刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2004-02-01 |
| 卷号 | 17期号:1页码:56-60 |
| 关键词 | Binding Ability Beta-cyclodextrin Naphthalene Derivatives Fluorescence Spectroscopy |
| ISSN号 | 1003-7713 |
| 英文摘要 | To enhance the binding ability of beta-cyclodextrin with naphthalene derivatives, a hydrophobic group to the rim of beta-cyclodextrin was added and the new beta-cyclodextrin compound-mono-6-beta-nitrobenzoyl-beta-cyclodextrin was synthesized. Its binding ability for 1:1 inclusion complexation with 1-naphthoic acid was evaluated in the KCl/HCl buffer solution (pH = 1.5, 0.1 mol/dm(3)) at 15degreesC by the spectrofluormetric titration. The results obtained indicated that mono-6-p-nitrobenzoyl-beta-cyclodextrin could strongly include 1-naphthoic acid in aqueous solution; the modification dramatically enhanced the original binding ability of native beta-cyclodextrin by a factor 9. The binding constants of mono-6-p-nitrobenzoyl-beta-cyclodextrin and other naphthalenes such as 1-methoxynaphthalene, 2-methoxynaphthalene, 1-N,N-dimethylaminonaphthalene and 1-N,N-dimethylaminonaphthalene were obtained from the time-resolved fluorescence. The high hinging ability of naphthalenes with NBCD make it is possible to assemble stable host-guest complexes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220151200012 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/81957]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Guo, QX |
| 作者单位 | 1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YH,Zhu, MZ,Ye, JP,et al. Study on the binding ability of mono-6-p-nitrobenzoyl-beta-cyclodextrin with naphthalene derivatives in aqueous solution[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2004,17(1):56-60. |
| APA | Wang, YH,Zhu, MZ,Ye, JP,&Guo, QX.(2004).Study on the binding ability of mono-6-p-nitrobenzoyl-beta-cyclodextrin with naphthalene derivatives in aqueous solution.CHINESE JOURNAL OF CHEMICAL PHYSICS,17(1),56-60. |
| MLA | Wang, YH,et al."Study on the binding ability of mono-6-p-nitrobenzoyl-beta-cyclodextrin with naphthalene derivatives in aqueous solution".CHINESE JOURNAL OF CHEMICAL PHYSICS 17.1(2004):56-60. |
入库方式： OAI收割
来源：化学研究所
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