Synthesis and characterization of (ZrW1.7W0.3O7H0.3)-W-VI-O-V(OH)(2) center dot 2H(2)O
文献类型：期刊论文
| 作者 | Zhao, HZ; Zhao, XH; Han, BX |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2004-06-10 |
| 卷号 | 25期号:6页码:1005-1009 |
| 关键词 | Heteropoly Blue (Zrw1.7w0.3o7h0.3)-w-v-o-v(Oh)(2) Center Dot 2h(2)o Epr |
| ISSN号 | 0251-0790 |
| 英文摘要 | A new sort of heteropoly blue compound, (ZrW1.7W0.3O7H0.3)-W-M-O-V (OH)(2) . 2H(2)O, was synthesized by the acidic-steam hydrothermal process and the microemulsion hydrothermal process. XRD pattern proves that the heteropoly blue compound has the same type of crystal structure as that of ZrMo2O7(OH)(2) . 2H(2)O. The rietveld refinement method was used to refine the crystal structure of the heteropoly blue compound. The bond parameters were calculated and the bond valences of atoms were obtained. The EPR result affirmed the subsistence of W-V ion in the new compound, and the molar ratio of W-V/W-M was determined by XPS. Combining with bond valences of atoms and IR spectra analysis, random hydroxylation of W-O3-H-0.15 exits in the molecule and the FTIR absorption spectra were assigned. |
| 语种 | 英语 |
| WOS记录号 | WOS:000222170400004 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82067]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, XH |
| 作者单位 | 1.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, HZ,Zhao, XH,Han, BX. Synthesis and characterization of (ZrW1.7W0.3O7H0.3)-W-VI-O-V(OH)(2) center dot 2H(2)O[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(6):1005-1009. |
| APA | Zhao, HZ,Zhao, XH,&Han, BX.(2004).Synthesis and characterization of (ZrW1.7W0.3O7H0.3)-W-VI-O-V(OH)(2) center dot 2H(2)O.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,25(6),1005-1009. |
| MLA | Zhao, HZ,et al."Synthesis and characterization of (ZrW1.7W0.3O7H0.3)-W-VI-O-V(OH)(2) center dot 2H(2)O".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 25.6(2004):1005-1009. |
入库方式： OAI收割
来源：化学研究所
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