Second-sphere coordination of the tris(5,5 '-diamino-2,2 '-bipyridine)iron complex with arene-carboxylate ligands through N-H center dot center dot center dot O hydrogen bonding
文献类型：期刊论文
| 作者 | Yang, XJ; Wu, B; Janiak, C; Sun, WH; Hu, HM |
| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
 |
| 出版日期 | 2004 |
| 卷号 | 630期号:11页码:1564-1572 |
| 关键词 | Second-sphere Coordination Supramolecular Chemistry Hydrogen Bonding Bipyridine Complexes Iron Complex |
| ISSN号 | 0044-2313 |
| DOI | 10.1002/zaac.200400175 |
| 英文摘要 | The tris(5,5'-diamino-2,2'-bipyridine)iron(II) complex [Fe(DABP)(3)](2+) can be engaged in hydrogen-bonding interactions from the amino groups to carboxylate-containing molecules as H-bond acceptors. This so-called second-sphere coordination of the metal complex is investigated here by using benzene-1,4-dicarboxylate (terephthalate, L-1), benzene-1,3-dicarboxylate (isophthalate, L-2), biphenyt-2,2'-dicarboxylate (L-3), and benzene-1,3,5-tricarboxylate (trimesate, L-4) anions for N-(HO)-O-... bonding. The second-sphere coordination of [Fe(DABP)(3)](2+) is further complemented by water molecules of crystallization in the isolated and structurally elucidated compounds of [Fe(DABP)(3)](L-1)(.)5H(2)O, [Fe(DABP)(3)](L-2)(.)8H(2)O, [Fe(DABP)(3)](L-1)(.)5H(2)O, and [Fe(DABP)(3)](3)(L-4)(2)(.)20H(2)O. The hydrogen-bonding between [Fe(DABP)(3)](2+) and the dicarboxylate anions (L-1-L-3) decreases from a three-dimensional supramolecular network (with V) to discrete units (with L 2 and V) with the increasing number of crystal water molecules. The tricarboxylate ligand L-4 is capable of capping the triangular face formed by the three amino groups in [Fe(DABP)(3)](2+). The solid-state structures of DABP(.)2H(2)O and 5,5'-bis(ethoxycarbonylamino)-2,2'-bipyridine (BEBP) are reported. |
| 语种 | 英语 |
| WOS记录号 | WOS:000224247600010 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82091]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Janiak, C |
| 作者单位 | 1.Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, XJ,Wu, B,Janiak, C,et al. Second-sphere coordination of the tris(5,5 '-diamino-2,2 '-bipyridine)iron complex with arene-carboxylate ligands through N-H center dot center dot center dot O hydrogen bonding[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2004,630(11):1564-1572. |
| APA | Yang, XJ,Wu, B,Janiak, C,Sun, WH,&Hu, HM.(2004).Second-sphere coordination of the tris(5,5 '-diamino-2,2 '-bipyridine)iron complex with arene-carboxylate ligands through N-H center dot center dot center dot O hydrogen bonding.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,630(11),1564-1572. |
| MLA | Yang, XJ,et al."Second-sphere coordination of the tris(5,5 '-diamino-2,2 '-bipyridine)iron complex with arene-carboxylate ligands through N-H center dot center dot center dot O hydrogen bonding".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 630.11(2004):1564-1572. |
入库方式： OAI收割
来源：化学研究所
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