Crosslinking of poly[(3-hydroxybutyrate)-co-(3-hydroxyvalerate)] using dicumyl peroxide as initiator
文献类型：期刊论文
| 作者 | Fei, B; Chen, C; Chen, S; Peng, SW; Zhuang, YG; An, YX; Dong, LS |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2004-07-01 |
| 卷号 | 53期号:7页码:937-943 |
| 关键词 | Poly [(3-hydroxybutyrate)-co-(3-hydroxyvalerate)] Crosslinking Initiator Mechanical Properties Biodegradation |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.1477 |
| 英文摘要 | In order to modify poly [(3-hydroxybutyrate)-co-(3-hydroxyvalerate)] (PHBV), the crosslinking of this copolymer was carried out at 160degreesC using dicumyl peroxide (DCP) as the initiator. The torque of the PHBV melt showed an abrupt upturn when DCP was added. Appropriate values for the gel fraction and crosslink density were obtained when the DCP content was up to 1 wt% of the PHBV. According to the NMR spectroscopic data, the location of the free radical reaction was determined to be at the tertiary carbons in the PHBV chains. The melting point, crystallization temperature and crystallinity of PHBV decreased significantly with increasing DCP content. The effect of crosslinking on the melt viscosity of PHBV was confirmed as being positive. Moreover, the mechanical properties of PHBV were improved by curing with DCP. When 1 wt% DCP was used, the ultimate elongation of PHBV increased from 4 to 11 %. A preliminary biodegradation study confirmed the total biodegradability of crosslinked PHBV. (C) 2004 Society of Chemical Industry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000222283900020 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82141]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Dong, LS |
| 作者单位 | 1.Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.NE Normal Univ, Coll Life Sci, Changchun 130024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fei, B,Chen, C,Chen, S,et al. Crosslinking of poly[(3-hydroxybutyrate)-co-(3-hydroxyvalerate)] using dicumyl peroxide as initiator[J]. POLYMER INTERNATIONAL,2004,53(7):937-943. |
| APA | Fei, B.,Chen, C.,Chen, S.,Peng, SW.,Zhuang, YG.,...&Dong, LS.(2004).Crosslinking of poly[(3-hydroxybutyrate)-co-(3-hydroxyvalerate)] using dicumyl peroxide as initiator.POLYMER INTERNATIONAL,53(7),937-943. |
| MLA | Fei, B,et al."Crosslinking of poly[(3-hydroxybutyrate)-co-(3-hydroxyvalerate)] using dicumyl peroxide as initiator".POLYMER INTERNATIONAL 53.7(2004):937-943. |
入库方式： OAI收割
来源：化学研究所
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