Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate
文献类型：期刊论文
| 作者 | Li, Q; Wu, PF; Wei, YG; Wang, Y; Wang, P; Guo, HY |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2004-04-01 |
| 卷号 | 7期号:4页码:524-527 |
| 关键词 | Polyoxometalates Organoimido Derivatives Dcc Supramolecular Assembly Crystal Structure |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2004.01.016 |
| 英文摘要 | A novel bifunctionalized arylimido derivative of hexamolybdate, (Bu4N)(2)[Mo6O17(dropNAr)(2)](2-) (Ar = o-CH3C6H4) 1, in which the two o-tolylimido groups are bounded to hexamolybdate at the cis positions, was synthesized by self-assembled metathesis of alpha-type octamolybdate ion and o-toluidine with DCC as a dehydration agent. The most interesting characteristic of 1 is that the cluster anions form dimers via the pi-pi stacking between one of its two phenyl rings, and four such dimers are linked in turn via C-H... O hydrogen bonding involving terminal hexamolybdate oxygen atoms into ring-like tetramers in the solid state. (C) 2004 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220553200018 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82175]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wei, YG |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Dept Chem, Beijing 100871, Peoples R China 2.Beijing Univ Chem Technol, Dept Chem, Beijing 100029, Peoples R China 3.Hubei Polytech Univ, Dept Bioengn, Wuhan 430068, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Q,Wu, PF,Wei, YG,et al. Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2004,7(4):524-527. |
| APA | Li, Q,Wu, PF,Wei, YG,Wang, Y,Wang, P,&Guo, HY.(2004).Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate.INORGANIC CHEMISTRY COMMUNICATIONS,7(4),524-527. |
| MLA | Li, Q,et al."Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate".INORGANIC CHEMISTRY COMMUNICATIONS 7.4(2004):524-527. |
入库方式： OAI收割
来源：化学研究所
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