Preparation of monolithic silica column and separation of benzene substituted compounds
文献类型：期刊论文
| 作者 | Gao, WH; Yang, GL; Yang, J; Liu, HY; Yin, JF; Yi, C |
| 刊名 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
 |
| 出版日期 | 2004-03-01 |
| 卷号 | 32期号:3页码:295-298 |
| 关键词 | Monolithic Silica Column Sol-gel Technology Pore Structure Normal-phase Chromatography |
| ISSN号 | 0253-3820 |
| 英文摘要 | A new approach of preparing monolithic silica column is reported, in which an improved sol-gel technology was adopted with tetramethoxysilane and polyethylene glycol as the matrix materials. The problems of crack and deformation in preparing the column were solved by using N,N-dimethylformamide and a heat treatment procedure. The methods of mesopore fabrication and column back pressure as a function of the flow-rate on the monolithic silica column were investigated, and the monolithic silica column was applied to separation of benzene substituted compounds which were baseline-separated in normal-phase chromatography. The results showed that the column prepared possessed bimodal pores structures with micrometer-size co-continuous through-pores and nanometer-size mesopores, straight appearance, high permeability and low column back pressure, high mechanical strength and column efficiency, which are well suited for high speed and high efficiency separations and analyses for compounds. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220700500005 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82177]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, GL |
| 作者单位 | 1.Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China 2.Hebei Univ Sci & Technol, Coll Biol Sci & Engn, Shijiazhuang 050018, Peoples R China 3.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, WH,Yang, GL,Yang, J,et al. Preparation of monolithic silica column and separation of benzene substituted compounds[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2004,32(3):295-298. |
| APA | Gao, WH,Yang, GL,Yang, J,Liu, HY,Yin, JF,&Yi, C.(2004).Preparation of monolithic silica column and separation of benzene substituted compounds.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,32(3),295-298. |
| MLA | Gao, WH,et al."Preparation of monolithic silica column and separation of benzene substituted compounds".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 32.3(2004):295-298. |
入库方式： OAI收割
来源：化学研究所
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