Synthesis and properties of novel conjugated poly (silylacetylene silazane)s
文献类型:期刊论文
作者 | Hu, JD; Zheng, ZM; Ma, T; Zhang, ZJ; Ye, JP; Wang, DY; Xie, ZM |
刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
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出版日期 | 2004-06-15 |
卷号 | 42期号:12页码:2897-2903 |
关键词 | Poly(Silylacetylene Silazane)s Conjugated Polymers Thermal Properties Optical Properties Conjugated Polymers Fluorescence Optics Thermal Properties |
ISSN号 | 0887-624X |
英文摘要 | A series of novel conjugated polymers, poly(silylacetylene silazane)s having different substituents, were prepared by ammonolysis of the corresponding alpha,omega-dichlorosilyleneacetylene oligomers. The structures and properties of the poly(silylacetylene silazane)s were characterized by Fourier transform infrared, H-1, C-13, Si-29 NMR, and elemental analyses, gel permeation chromatography, thermogravimetric analysis, differential scanning calorimetry, and spectrofluorophotometry. The resulting polymers had good thermal properties and were moderately fluorescent. Their thermal stability was improved, and obvious red shift was observed when a phenyl substituent was attached on a silicon atom of polymers in the emission spectra. These polymers have the potential to be used as light-emitting materials with good thermal stability. (C) 2004 Wiley Periodicals, Inc. |
语种 | 英语 |
WOS记录号 | WOS:000221769700006 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/82251] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Xie, ZM |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Engn Phys, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Hu, JD,Zheng, ZM,Ma, T,et al. Synthesis and properties of novel conjugated poly (silylacetylene silazane)s[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2004,42(12):2897-2903. |
APA | Hu, JD.,Zheng, ZM.,Ma, T.,Zhang, ZJ.,Ye, JP.,...&Xie, ZM.(2004).Synthesis and properties of novel conjugated poly (silylacetylene silazane)s.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,42(12),2897-2903. |
MLA | Hu, JD,et al."Synthesis and properties of novel conjugated poly (silylacetylene silazane)s".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 42.12(2004):2897-2903. |
入库方式: OAI收割
来源:化学研究所
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