中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystalline organic molecular thin film with electrical switching property: Scanning probe microscopy and optical spectroscopy study

文献类型:期刊论文

作者Li, JC; Xue, ZQ; Wang, KZ; Wang, ZM; Yan, CH; Song, YL; Jiang, L; Zhu, DB
刊名JOURNAL OF PHYSICAL CHEMISTRY B
出版日期2004-12-16
卷号108期号:50页码:19348-19353
ISSN号1520-6106
DOI10.1021/jp047733g
英文摘要We report on the growth and characterization of crystalline 1, 1 -dicyano-2,2-(4-dimethylaminophenyl)ethylene (DDME) thin film with electrical switching property. X-ray diffraction analysis indicates that bulk singlecrystal DDME belongs to monoclinic, space group P2(1), and Z = 2 structure. Optical spectroscopy shows that the film chemical structure is consistent with that of the powder material, suggesting that DDME material is very stable during the vacuum thermal deposition process. Scanning probe microscopy and transmission electron microscopy observations reveal that the as-deposited film has extended crystal structure and smooth surface morphology in micrometer scale. Parallel molecular stacking structure is repeatedly observed in the film surfaces with the axis of the molecular stack parallel to the substrate. The ac crystal plane is found to be one of the most stable surfaces of the DDME film in ambient conditions. Nanometer scale data storage is realized on the film by applying pulse voltage between the STM tip and the substrate. The switching mechanism is briefly discussed.
语种英语
WOS记录号WOS:000225695100043
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/82261]  
专题中国科学院化学研究所
通讯作者Li, JC
作者单位1.Peking Univ, Dept Elect, Beijing 100871, Peoples R China
2.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
3.Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
4.Chinese Acad Sci, Organ Solid Lab, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Li, JC,Xue, ZQ,Wang, KZ,et al. Crystalline organic molecular thin film with electrical switching property: Scanning probe microscopy and optical spectroscopy study[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2004,108(50):19348-19353.
APA Li, JC.,Xue, ZQ.,Wang, KZ.,Wang, ZM.,Yan, CH.,...&Zhu, DB.(2004).Crystalline organic molecular thin film with electrical switching property: Scanning probe microscopy and optical spectroscopy study.JOURNAL OF PHYSICAL CHEMISTRY B,108(50),19348-19353.
MLA Li, JC,et al."Crystalline organic molecular thin film with electrical switching property: Scanning probe microscopy and optical spectroscopy study".JOURNAL OF PHYSICAL CHEMISTRY B 108.50(2004):19348-19353.

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来源:化学研究所

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